The aim of this work is to make a visual investigation of the fire behavior during the extinguish process with water mist at different temperatures, different diameters of the nozzle and different angles of diffusion jet, too. It was used a numerical simulation approach to analyze 24 scenarios regarding the influence of mist water in fire extinguish process. The main test was focused on a given enclosure with dimensions of 1.0 × 1.0 × 3.0 m and the fire source placed inside, in the middle. The enclosure is considered opened on the upper part. From the numerical simulation values, we concluded the best scenario in fire extinguish process using water mist.