Mixing state and effective density of aerosol particles during the Beijing 2022 Olympic Winter Games

Abstract

Abstract. Mixing state and density are two key parameters of aerosol particles affecting their impacts on radiative forcing and human health. Here a single particle aerosol mass spectrometer in tandem with a differential mobility analyzer and an aerodynamic aerosol classifier was deployed during the Beijing 2022 Olympic Winter Games (OWG) to investigate the impacts of emission controls on particle mixing state and density. Nearly 760,000 particles were detected, which were classified into seven major classes. Our results showed the dominance of carbonaceous particles comprising mainly Total-EC (13.4 %), Total-OC (10.5 %) and Total-ECOC (47.1 %). Particularly, the particles containing organic carbon and sulfate were enhanced significantly during OWG although those from primary emissions decreased. The composition of carbonaceous particles also changed significantly which was characterized by the decreases in EC-NS, KEC-N, and amine-containing particles, and increase in ECOC-NS. This result indicates that emission controls during OWG reduced the mixing of elemental carbon (EC) with inorganic aerosol species and amines, yet increased the mixing of EC with organic aerosol. The average effective density (ρeff) of aerosol particles (150–300 nm) was 1.20 g cm−3 with higher values during OWG (1.26 g cm−3) due to the increase in secondary particle contribution. The two types of fresh particles, i.e., Total-EC and high molecular weight organic matter presented the lowest ρeff (0.97 g cm−3 and 0.87 g cm−3, respectively). In addition, the ρeff of most particles increased as the increases in pollution levels and relative humidity, yet varied differently for different types of particles, highlighting the impacts of aging and formation processes on the changes of particle density and mixing state.