Mixed-valent titanium tellurium oxides, Ti1-Te Te3O8+ (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization

From AgTeO2F and Ag2(TeO2F2) to Ag3F3(TeF6)(TeO2)12: the first silver tellurite oxyfluorides with linear and nonlinear optical properties

“…16–20 Metal tellurites can also display plentiful structure types because the polar oxyanions can join together by condensation to generate 0D clusters, 21–23 1D chains, 24–27 2D layers 28,29 and even 3D frameworks. 30,31…”

“…[16][17][18][19][20] Metal tellurites can also display plentiful structure types because the polar oxyanions can join together by condensation to generate 0D clusters, [21][22][23] 1D chains, [24][25][26][27] 2D layers 28,29 and even 3D frameworks. 30,31 Fluorine, as the most electronegative element, could replace oxygen ligands due to their similar ionic radii. [32][33][34] When fluorine atoms are introduced into oxide compounds, fluoride compounds often can display excellent comprehensive performance and abundant structure types, [35][36][37][38] such as RbTeMo 2 O 8 F (27 × KDP, 3.63 eV), 39 Ba(MoO 2 F) 2 (TeO 3 ) 2 (7.8 × KDP, 2.96 eV), 40 and BaF 2 TeF 2 (OH) 2 (3 × KDP, 5.9 eV) 41 in metal tellurites.…”