Mixed‐Tetravalent Cs2RumPt1−mX6 (X = Cl−, Br−)‐Based Vacancy‐Ordered Halide Double Perovskites for Enhanced Solar Water Oxidation
Jigar Shaileshkumar Halpati,
Nandhini Shanmugam,
Manasa Manoj
et al.
Abstract:Vacancy‐ordered halide double perovskites (VOPs) are reported to be suitable for photoelectrochemical (PEC) water splitting, due to their panchromatic visible absorption and stability in electrolyte. In this work, ruthenium‐based VOP, Cs2RuX6 (X = Cl−, Br−), is reported for PEC water splitting, and the material is found to be extremely stable in harsh pH media, between pH1 and pH11. The PEC devices made with these materials show good photogenerated hole transport to electrolyte; however, the photovoltage remai… Show more
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