Mixed Systems Based on Erucyl Amidopropyl Betaine and Nanoparticles: Self‐Organization and Rheology

Gaynanova, Gulnara A.; Valiakhmetova, Alsu; Kuryashov, D. A.; Bashkirtseva, N. Yu.; Zakharova, L. Ya.

doi:10.1007/s11743-015-1743-1

Cited by 19 publications

(11 citation statements)

References 47 publications

(56 reference statements)

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“…When the nanoparticles have opposite charges with the headgroup of surfactants, the electrostatic interaction prevails, and the surfactants are electrostatically attracted to the surface of nanoparticles through charged head groups. 245,289,301,302 In this case, surfactant bilayers wrapping nanoparticles are formed (Figure 11(a)). When the nanoparticles are uncharged hydrophobic particles, the hydrophobic interaction is dominant, and the surfactants are chemically adsorbed on the particle surfaces through hydrophobic tails to form surfactant monolayers (Figure 11(c)).…”

Section: Counterion Salt Effectmentioning

confidence: 99%

“…Several hypotheses about the interaction mechanism between nanoparticles and WLMs have been put forward in the literature. − It is usually divided into two stages: surfactant adsorption and micelles fusion. When the nanoparticles have opposite charges with the headgroup of surfactants, the electrostatic interaction prevails, and the surfactants are electrostatically attracted to the surface of nanoparticles through charged head groups. ,,, In this case, surfactant bilayers wrapping nanoparticles are formed (Figure (a)). When the nanoparticles are uncharged hydrophobic particles, the hydrophobic interaction is dominant, and the surfactants are chemically adsorbed on the particle surfaces through hydrophobic tails to form surfactant monolayers (Figure (c)). , Meanwhile, when the surface charge of nanoparticles is the same as that of surfactants, surfactants can still adsorb on the surface through hydrophobic interaction to form semimicelles (Figure (b)). , In the next stage, the nanoparticles coated by surfactants interact with WLMs formed by surfactant self-assembly (Figure (d) and (e)).…”

Section: High-temperature-resistant Ves Fracturing Fluidsmentioning

confidence: 99%

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Review on High-Temperature-Resistant Viscoelastic Surfactant Fracturing Fluids: State-of-the-Art and Perspectives

Liu

et al. 2023

Energy Fuels

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A viscoelastic surfactant (VES) fluid is an important part of a water-based fracturing fluid. As oil and gas exploration expands into deep, high-temperature, low-permeability reservoirs, the conventional VES fracturing fluid has shown great limitations. The high-temperature-resistance mechanisms of the high-temperature-resistant VES fracturing fluids in publicly available literature were analyzed from five aspects: single-chain surfactant system, oligomeric surfactant system, counterion effect, blended surfactant system, and nano-enhanced VES system. The friction-reduction performance, sand-carrying performance, gel-breaking performance, and core-damage performance of these systems were summarized. The results show that oligomeric surfactants with a monounsaturated hydrophobic long chain (>C21) are most likely to be used for VES fracturing fluids in high-temperature reservoirs, but the loading of the surfactants is still relatively high (3–5 wt %). By reducing the repulsion among polar headgroups to effectively decrease the area of head groups, or/and penetrating into the nonpolar cores based on hydrophobic interaction to increase the average hydrophobic volume of hydrophobic tails, counterions affect the performance of VESs. The aromatic counterion salts are preferred choices for improving the temperature resistance, friction reduction, and suspended sand performance of VES fluids. The blended surfactant/synthetic polymer systems based on noncovalent interaction improve the temperature resistance of VES fluids and reduce the loading of the surfactants to a certain extent. Based on the “pseudo-cross-linking” of nanomaterials and wormlike micelles, a very small amount of nanomaterials can improve the temperature resistance of VES fluids and reduce the loading of the surfactants. The most essential and effective method to improve the temperature resistance of VES fluids for fracturing is the molecular structure design based on the packing parameter theory. However, the synthesis process or route still needs further optimization to reduce production costs. In addition, given the excellent performance of VES fluids enhanced by nanomaterials, further research should be conducted on the influence mechanism of nanomaterial type and geometric features on the performance of VESs, as well as the potential harmfulness of nanomaterials, to promote the field-scale application of nano-enhanced VES fluids.

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Section: Counterion Salt Effectmentioning

confidence: 99%

Section: High-temperature-resistant Ves Fracturing Fluidsmentioning

confidence: 99%

Review on High-Temperature-Resistant Viscoelastic Surfactant Fracturing Fluids: State-of-the-Art and Perspectives

Liu

et al. 2023

Energy Fuels

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“…At the same time, zwitterionic surfactants, which are low-toxic, biodegradable, and safe even for the sensitive child skin, are more promising in environmental terms [24]. However, just one work devoted to the effect of nanoparticles on the rheological properties of the solutions of zwitterionic surfactants has been published so far [25]. It was shown that the addition of negatively charged silica nanoparticles (0.3-0.8 wt %) with a radius of 12 nm to a solution of the wormlike micelles of erucyl amidopropyl dimethyl betaine with a long C22 tail increases the viscosity of the system twofold.…”

Section: Introductionmentioning

confidence: 99%

“…The aim of this work is to study the effect of nanoparticles on the rheological properties and structure of wormlike micelles based on a biodegradable zwitterionic surfactant with a long C18 tail, oleyl amidopropyl dimethyl carboxybetaine (OAB), obtained from biorenewable resources, vegetable oils, with a small addition of an anionic surfactant, sodium dodecyl sulfate (SDS). As opposed to the overwhelming majority of previous works on nanocomposite systems based on wormlike surfactant micelles [17][18][19][20][21][22][23]25], platelike nanoparticles with a high specific surface compared with commonly used spherical particles were used as a filler. This provided a larger surface for interaction with micellar chains.…”

Section: Introductionmentioning

confidence: 99%

Networks of Micellar Chains with Nanoplates

et al. 2021

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Nanocomposite networks of surfactant micellar chains and natural bentonite clay nanoplates are studied by rheometry, small-angle neutron scattering, and cryogenic transmission electron microscopy. It is shown that, in an aqueous medium in the presence of a small part of an anionic surfactant, sodium dodecyl sulfate, the molecules of a biodegradable zwitterionic surfactant, oleyl amidopropyl dimethyl carboxybetaine, form micron-length living micellar chains which entangle and form a network possessing well-defined viscoelastic properties. It is found that addition of negatively charged clay nanoplates leads to an increase in viscosity and relaxation time by an order of magnitude. This is explained by the incorporation of the nanoplates into the network as physical multifunctional crosslinks. The incorporation occurs via the attachment of semispherical end-caps of the micelles to the surface of the particles covered with a surfactant layer, as visualized by cryogenic transmission electron microscopy. As the amount of nanoplates is increased, the rheological properties reach plateau; this is associated with the attachment of all end parts of micelles to nanoplates. The developed nanocomposite soft networks based on safe and eco-friendly components are promising for various practical applications.

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“…Compared with the pure micellar solution, the system with a moderate concentration of nanoparticles has a larger zero‐shear viscosity. Gaynanova et al investigated the aggregation behavior of a compound system constructed by wormlike micelles and silica nanoparticles (Gaynanova et al, ). They found that electrostatic interaction caused the adsorption of zwitterionic surfactants on the surface of the nanoparticles.…”

Section: Introductionmentioning

confidence: 99%

Effect of Silica Nanoparticles on Wormlike Micelles with Different Entanglement Degrees

Zhao

Gao

Dai

et al. 2019

J Surfact & Detergents

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Enhancing the viscoelastic properties of wormlike micelles by adding nanoparticles has been widely reported. Various mechanisms have been proposed to explain how nanoparticles strengthen the network formed by wormlike micelles. It remains unclear whether nanoparticles produce the same effect on systems with different entanglement degrees. To clarify this issue, the concentration of potassium chloride was used to control the entanglement degree of wormlike micelles. The rheological behavior of different nanoparticle‐enhanced wormlike micellar systems (NEWMS) was investigated using rheology. Three critical parameters including zero‐shear viscosity (η0), relaxation time (τR), and contour length (L) were calculated to analyze the effect of nanoparticles on the different wormlike micellar systems. An appropriate mechanism describing the interaction between nanoparticles and wormlike micelles with different structures was proposed.

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Mixed Systems Based on Erucyl Amidopropyl Betaine and Nanoparticles: Self‐Organization and Rheology

Cited by 19 publications

References 47 publications

Review on High-Temperature-Resistant Viscoelastic Surfactant Fracturing Fluids: State-of-the-Art and Perspectives

Review on High-Temperature-Resistant Viscoelastic Surfactant Fracturing Fluids: State-of-the-Art and Perspectives

Networks of Micellar Chains with Nanoplates

Effect of Silica Nanoparticles on Wormlike Micelles with Different Entanglement Degrees

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