Mixed Polymers and Vulcanizable Plasticizers

Garvey, B. S.; Alexander, Chen; Küng, F. E.; Henderson, David

doi:10.1021/ie50380a023

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Application To Vulcanization1

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1944

1991

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Cited by 10 publications

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“…Accompanying phenomena such as isomerization (9), cyclization (15), and degradation reactions (reversion) may occur, and account for the differences observed under various conditions of vulcanization in the early stages or soft rubber range. These secondary reactions probably become very important in the ebonite stage.…”

Section: Application To Vulcanizationmentioning

confidence: 99%

Chemistry of Sulfur-Olefin Reactions

Armstrong¹,

Little²,

Doak³

1944

Ind. Eng. Chem.

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Section: Application To Vulcanizationmentioning

confidence: 99%

Chemistry of Sulfur-Olefin Reactions

Armstrong¹,

Little²,

Doak³

1944

Ind. Eng. Chem.

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Solvent‐resistant rubbers obtained by the use of metallic soaps

Korb¹

1962

J of Applied Polymer Sci

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At present, solvent‐resistant rubbers are obtained only by the introduction of polar groups in the polymer chain. These groups impair some physical properties of the rubber. A new way is suggested for obtaining solvent‐resistant rubbers by using nonpolar elastomers compounded with metallic soaps. These soaps can be considered polymeric materials, whose long chains are built up by weak coordinate bonds, which can be easily broken and reformed in contact with solvents. In this way a layer of solvent‐swollen soap is formed over the soap‐compounded vulcanizate, which prevents further attack. An explanation of the above behavior is given on the basis of the crystallization tendency of the metallic soap.

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