Let D be an effective Cartier divisor on a regular quasi-projective scheme X of dimension d ≥ 1 over a field. For an integer n ≥ 0, we construct a cycle class map from the higher Chow groups with modulus {CH n+d (X mD, n)} m≥1 to the relative K-groups {K n (X, mD)} m≥1 in the category of pro-abelian groups. We show that this induces a proisomorphism between the additive higher Chow groups of relative 0-cycles and the reduced algebraic K-groups of truncated polynomial rings over a regular semi-local ring which is essentially of finite type over a characteristic zero field.