A note on versions:The version presented here may differ from the published version or from the version of record. If you wish to cite this item you are advised to consult the publisher's version. Please see the repository url above for details on accessing the published version and note that access may require a subscription. Specifically, a switching temperature (Ts) of ~42 °C (6 wt. % HPC) was recorded, the measured transmittance decreases from ~ 90% to ~20%, with the temperature of the reflective layer increasing from 20°C to 60°C. No hysteresis in optical property was observed upon heating-cooling cycle of HPC membrane samples. The measured reflectivity increased with heating from ~10 % below the Ts to ~50 % above the Ts (for 6 wt. % HPC). These features indicate that the as-prepared HPC based thermotropic hydrogel layer holds great potential for application in next generation BICPV smart windows.