Mineralogy and genesis of the Ni–Co lateritic regolith deposit of the Çaldağ area (Manisa, western Anatolia), Turkey

Abstract

The Çaldağ Ni–Co deposit is characterized by a reddish brown oxide lateritic regolith, containing residual Ni deposit formed by the intense tropical weathering of peridotites. Nickel–Co ore is associated with transported ferricrete during the late Paleocene – middle Eocene, represented by colloform Fe oxides and residual lateritization during the Oligocene. The lateritic regoliths are developed over dunitic ultramafic rocks and consist mainly of smectite, berthierine, kaolinite, gypsum, pyrite, takovite, and pecoraite. These units were examined using polarized-light microscopy, X-ray diffraction, scanning and transmission electron microscopy, and geochemical methods. Mineralogical zonation from the base of the profile upwards has the following zones: ultramafic bedrocks, serpentinized ultramafic rocks (saprock), saprolite, carbonate- and sulfide-bearing zone, ferruginous saprolite zone, and silcrete. In addition, Fe oxides, smectite and opal-CT, and quartz increase towards the surface, whereas olivine, pyroxene, and serpentine decrease upwards in response to chemical weathering. Nickel–Co mineralization associated with Fe oxides and smectitic clays formed under wet and dry conditions, respectively, as a result of an increased Fe2O3 + Al2O3 + Ni + Co/MgO ratio. Field observations and mineralogical and geochemical analyses reveal that the smectite formed under basic conditions was controlled by multistage chemical weathering of ultramafic and volcanic rocks and by the concentrations of Si, Al, Fe, and Mg. Locally, concentrations of S in conjunction with Fe and Ca resulted in precipitation of goethite–hematite, gypsum, and pyrite in dissolution voids in association with smectite under acidic conditions that developed in a well-drained system.

Pemodelan dan Estimasi Sumberdaya Nikel Laterit Berdasarkan Kandungan Ni dan Fe dengan Menggunakan Metode Kriging di PT Putra Perkasa Abadi, Kecamatan Langgikima, Kabupaten Konawe Utara, Provinsi Sulawesi Tenggara

“…Nikel laterit merupakan salah satu mineral logam hasil dari proses pelapukan kimia batuan ultramafik yang mengakibatkan pengkayaan unsur Ni, Fe, Mn, dan Co secara residual dan sekunder (Syafrizal et al, 2011;Burger, 1996). Nikel laterit dicirikan oleh adanya logam oksida yang berwarna coklat kemerahan mengandung Ni dan Fe (Cahit et al, 2017). Salah satu faktor yang mempengaruhi pembentukan endapan nikel laterit adalah morfologi, batuan asal dan tingkat pelapukan (Kurniadi et al, 2017).…”

Teknologi Hijau Pengelolaan Bijih Nikel Laterit (Nickel Laterite Spent Ore Treatment “Green Technology”)

“…Nikel laterit merupakan mineral logam hasil dari proses pelapukan dan pengayaan mineral pada batuan ultramafic yang mengakibatkan pengkayaan unsur Ni, Fe, Mn, Co secara residual dan sekunder (Wang et al, 2023). Nikel laterit dicirikan oleh adanya logam oksida yang berwarna cokelat kemerahan mengandung Ni dan Fe (Helvacı et al, 2017). Proses terbentuknya nikel laterit dimulai dari proses pelapukan yang intensif pada batuan peridotit (Liang et al, 2022).…”