Mineralization of Poly(ɛ-caprolactone)/Adipate Modified Starch Blend in Agricultural Soil

Biodegradation Study of a Novel Poly-Caprolactone-Coffee Husk Composite Film

“…Moreover, processing ability of PCL by extrusion as well as its compatibility with other materials, make it an attractive polymer for several applications 8,9 . PCL-starch blends have been studied and the effects of starch on mechanical properties and biodegradation time were evaluated [10][11][12][13] . In addition, PCL-natural-organic fillers (eggshell, coconut, abaca, kenaf, seaweed, rice straw, sisal) composites have also been investigated 2,[14][15][16][17][18][19][20] .…”

Kinetics study of Ti[O(CH2)4OCHCH2]4 initiated ring‐opening polymerization of ε‐caprolactone by differential scanning calorimetry

“…Because of their biodegradability, permeability, and good compatibility with many other polymers, poly(ε‐caprolactone) (PCL), its copolymers, and PCL‐based blends have been investigated worldwide for all kinds of purpose, such as pharmacological, biomedical, agricultural, and environmental,1–5 which provide PCL a great potential of application. Up to now, there are many ways to prepare PCL, but the ring‐opening polymerization (ROP) of ε‐caprolactone initiated by metal alkoxides, such as aluminum,6, 7 tin,8 magnesium,9 zinc,10 and titanium derivatives,8, 11 is the most practical and convenient strategy.…”

Recent advances in nanocellulose processing, functionalization and applications: a review

“…In contrast to the 100% pure polymer content, improved rigidity, toughness, strength, barrier features, and even flame retardancy can be achieved by adding nanomaterials in the form of fillers in composite materials. 212,220,221 As a consequence of the large surface area of the nanoparticles, the introduction of a small proportion of nanomaterials is necessary for these changes. In contrast to carbon nanotubes, the strength of wood cellulose nanofibers is only a quarter of that of the carbon nanotubes, but the price of cellulose nanofibers is lower than the price of carbon nanotubes, making the woodbased nanomaterial more desirable for unique applications.…”

“…Although, the low thermal stability of cellulose nanomaterials can, at high temperatures, restrict the usage and manufacturing conditions of their nanocomposites. 216,220 This problem is especially important for H 2 SO 4 hydrolyzed CNC, which, compared to the raw starting material or other types of nanocellulose, exhibits a dramatically reduced thermal stability. This is due to the classes of sulfate esters.…”