Mineralization of CCl4 and CCl2F2 on Solid Surfaces

Gäb, Siegmar; Schmitzer, J.; Turner, Walter V.; Körte, F.

doi:10.1515/znb-1980-0803

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1983

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Cited by 13 publications

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“…(OH)3 + 3HC1 [11] Reaction [10] and [11] form a catalytic cycle, with the HC1 being regenerated to continue to attack on the aluminum (64,65). The same hazard is present if chlorinated solvents such as CH3CC13 come in contact with aluminum either during or following manufacturing processes (66,67). In Fig.…”

Section: Cmentioning

confidence: 99%

Corrosion Mechanisms for Aluminum Exposed to the Atmosphere

Graedel

1989

J. Electrochem. Soc.

171

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Upon exposure to the indoor or outdoor atmosphere and during some manufacturing processes, aluminum degrades with the formation of a variety of corrosion products. This paper relates those products to the atmospheric constituents that are their precursors, explores the chemical processes involved in corrosion product formation, and evaluates the magnitudes of the sources for the major corrosive anions. A three-layer structure is identified: the aluminum itself and its native oxide, the corrosion layer atop the oxidized aluminum, and a surface contamination layer. At low to moderate humidities, this last layer can be pictured as a moist agglomeration of deposited particles and common ionic compounds. At high

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Section: Cmentioning

confidence: 99%