“…The chemistry varies in mineral, organic, and water content as one moves from the occlusal surface of the enamel to the DEJ. Many researchers have characterized the chemistry of human enamel as a function of position, 11,12,13,14,15,16 and in some cases the results have been correlated with spatial variations in the mechanical properties of enamel. 10,15,17,18,19 Habelitz et al 20 showed Young's moduli and hardness were lower in the inter-rod enamel than in the head of the enamel rod.…”