Mineral Composition Evaluation in Energy Drinks Using ICP OES and Chemometric Tools

Martins, Alexsandro Sozar; Pereira, João B.; Gomes, A. A.; Carvalho, Fábio Israel Martins; Filho, Heronides Adonias Dantas; Dantas, Kelly das Graças Fernandes

doi:10.1007/s12011-019-01770-y

Cited by 6 publications

(4 citation statements)

References 30 publications

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“…Arsenic was detected in tested samples with the highest concentration among target elements. Obtained TAs, TCr, and TSb results are in a good accordance with the data available from the literature regarding those element concentrations in various soft drinks and mineral water samples [9,[22][23][24][25][26].…”

Section: Discussionsupporting

confidence: 88%

Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

et al. 2020

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Packing material can release certain elements such as As, Cr, or Sb into its content and, thus, contaminate the drinking water. The effect of As, Cr, and Sb on human health depends highly on the chemical species in which these elements are introduced into the body. For the above reasons quantification and speciation of As, Cr, and Sb in flavored and functional drinking water samples is an important issue. Total, inorganic, and organic species of As, Cr, and Sb including As(III), As(V), Cr(VI), Sb(III), and Sb(V) were studied in flavored and functional drinking waters. Analyses of total As, Cr, and Sb were conducted using inductively coupled plasma mass spectrometry (ICP-MS) according to ISO 17294-2:2016. The speciation analysis of arsenic, chromium, and antimony in bottled flavored and functional drinking waters was conducted with the use of the elemental (HPLC/ICP dynamic reaction cell (DRC) MS) and molecular (electrospray ionization MS/MS) mass spectrometry. Concentrations of total As, Cr, and Sb (µg∙L−1) in waters studied were in the ranges 0.0922 ± 0.0067 to 8.37 ± 0.52, 0.0474 ± 0.0014 to 1.310 ± 0.045, and 0.0797 ± 0.0026 to 1.145 ± 0.019, respectively. Speciation analysis showed that, apart from the toxic ionic species, known and unknown organic species were present in test samples. The risk assessment results proved that there is no risk associated with consumption of these tested beverages in terms of the non-carcinogenic effect of total and inorganic or organic species of As, Cr, and Sb.

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Section: Discussionsupporting

confidence: 88%

Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

et al. 2020

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“…For the quantification of caffeine, a validated HPLC method was utilized, providing accurate, reliable, reproducible, and sensitive results [26]. Moreover, in the determination of element content, an ICP-OES method was used to determine the element content, allowing for simultaneous detection of elements [27]. Nonetheless, it is important to consider that both methods might have limitations, namely matrix effects, depending on the analyzed sample [28,29].…”

Section: Resultsmentioning

confidence: 99%

“…In our study, the selection of elements for analysis was driven by several factors, including their relevance to beverage safety, potential health risks, and the availability of established regulatory limits. We aimed to focus on elements that are commonly found in beverages, according to previous studies [27,30,31], and may pose health hazards if present in excessive amounts. Tin (Sn) was not studied since, as a potentially integral part of the packaging material, it adheres to strict regulations and standards set by food safety authorities.…”

Section: Resultsmentioning

confidence: 99%

Determination of Caffeine and Elements in Hypertonic, Isotonic, and Hypotonic Beverages

Athanasiadis,

Chatzimitakos,

Kalompatsios

et al. 2023

Beverages

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The study focused on the examination of eight commercial hypertonic, isotonic, and hypotonic beverage samples that were packaged in aluminum cans or polyethylene terephthalate (PET) bottles. The pH value, caffeine content, and concentration of thirty elements were determined. Caffeine quantification was performed by a high-performance liquid chromatography method. Element determination was conducted by using inductively coupled plasma–optical emission spectrometry. The results showed that pH values were much more acidic in all samples, ranging from 2.68 to 3.97. Caffeine concentrations ranged from 0.02–38.93 mg/100 mL between the samples and were found to be below the acceptable daily level (~400 mg) established by the relevant food regulatory authority. The measurable quantity of caffeine (~10 mg/100 mL) was found in two functional beverage samples where caffeine was labeled as an ingredient. Element concentration varied with statistically significant differences (p < 0.05) among all samples. Elements such as arsenic, cadmium, chromium, and lead were measured below the corresponding permissible levels set by the European Commission; however, daily consumption of functional beverages should be examined to deteriorate several health risks. Aluminum was quantified above the parametric value by 21 to 117% in the canned samples, whereas antimony was only measured in PET-bottled samples at approximately 3 μg/L. Multivariate methods were applied to investigate any possible correlation between the samples and the examined parameters. Strong positive correlations with statistically significant differences (R > 0.9, p < 0.05) were observed between zinc and copper and between calcium and silver. Finally, similarities and differences between the samples and the examined parameters resulted in satisfactory discrimination of them regarding not only their caffeine content but also their tonicity. Excessive consumption of functional beverages could represent a major public health issue due to elevated amounts of caffeine and elements. Consequently, the results of this research could facilitate the formulation of stricter standards in beverage consumption by revealing potential health hazards to consumers.

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“…Проведенные в Бразилии и Иране исследования минерального состава энергетических напитков показали, что в них высокое содержание натрия, калия, кальция и магния. При этом напитки, хранящиеся в металлических банках, содержат более высокий уровень алюминия и магния, в то время как напитки, разлитые в бутылки из полиэтилентерефталата, имеют более высокое содержание калия [3]. Концентрации Pb, Ni, Cr, Cu, Ba, Hg, Cd и As в образцах напитков были ниже предела, установленного USEPA, FAO/WHO, CA и NSI (Министерством сельского хозяйства США, Продовольственной и сельскохозяйственной организацией / Всемирной организацией здравоохранения, Кодекс Алиментариус и Национальным стандартом Ирана).…”

Section: Introductionunclassified

Диаграмма Связей В Сравнительной Оценке Качества Безалкогольных Тонизирующих Напитков

Резниченко¹,

Астахова²,

Маликова³

2022

Ползуновский Вестник

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Представлены результаты сравнительной оценки качества тонизирующих безалкогольных напитков, реализуемых отечественным ритейлом. Требования современного потребителя вынуждают производителей расширять ассортиментную линейку пищевых продуктов, в том числе и тонизирующих напитков, что формирует высокий уровень конкуренции на данном продовольственном сегменте рынка. Применение инструментов квалиметрического анализа позволяет установить связь потребительских критериев и нормируемых показателей, выявить определяющие критерии выбора продукта. Объекты и методы исследования. Объектами исследования при сравнительной оценке являлись образцы безалкогольных тонизирующих напитков. В качестве метода исследования применяли метод квалиметрического анализа – диаграмму связей. Оценку качества тонизирующих напитков проводили по ГОСТ Р 52844-2007. Органолептические показатели и полноту налива оценивали по ГОСТ 6687.5; анализ маркировки выполняли на соответствие требованиям ТР ТС 022/2011 «Пищевая продукция в части ее маркировки»; анализ упаковки – по ТР ТС 005/2011 «О безопасности упаковки». Результаты и их обсуждение. Выявлены связи между потребительскими характеристиками и факторами, влияющими на их формирование с помощью инструмента квалиметрического анализа – диаграммы связей. Предложенная диаграмма, отражает качество продукции, как совокупность потребительских критериев важных для удовлетворения спроса покупателя и отдельных свойств напитка, регламентированных нормативными документами (неизвестными потребителям, но влияющих на потребительские характеристики). Диаграмма связей легла в основу разработанной балловой шкалы для оценки качества безалкогольных тонизирующих напитков и анализа потребительских критериев.Выводы и рекомендации. Предложена балловая шкала оценки тонизирующих напитков, отражающая показатели диаграммы связей. Выявлены недостатки в маркировке образцов тонизирующих напитков, отсутствии информации важной для потребителя. Сравнительная оценка качества позволила ранжировать исследуемые образцы в порядке снижения качественных показателей Практическая значимость работы заключается в получении новых данных важных для производителя при выпуске конкурентоспособной продукции, отвечающей потребительским критериям качества.

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Mineral Composition Evaluation in Energy Drinks Using ICP OES and Chemometric Tools

Cited by 6 publications

References 30 publications

Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

Total Versus Inorganic and Organic Species of As, Cr, and Sb in Flavored and Functional Drinking Waters: Analysis and Risk Assessment

Determination of Caffeine and Elements in Hypertonic, Isotonic, and Hypotonic Beverages

Диаграмма Связей В Сравнительной Оценке Качества Безалкогольных Тонизирующих Напитков

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