MINDO/2 Treatment of Species Present in Carbon Vapor

Abstract

ylidation also); m.p. -lO°C, b.p. 35 "Ci0.1 torr; 1H-NMR (without solvent): 6 CH3P -75 Hz, d, J(H3CP) 12.1; 6 C H + 57.5 Hz, d, J(HCP) 6.5; 6 CH3Si, + 6 Hz, s; 6 CH3Sip + 8 Hz, s; intensity ratio 9:l: 6:9.(3) is formed from (CH3)3PCH2(52 mmoles) and (CH3)5Si2Cl (35 mmoles) as a colorless nondistillable liquid (yield 61 %); d, J(H2CP) 15.5; 6 C H + 65 Hz, d, J(HCP) 6.5; 6 CH3SizCH2