“…Thus, much attention has been focused on the conversion of P (V) =O to P (III) 15 , 16 ( Scheme 1 a), including the use of silanes and siloxanes such as HSiCl 3 , 22 − 25 HSiCl 3 /Ph 3 P, 26 Si 2 Cl 6 , 24 , 27 Si 2 Me 6 with CsF/TBAF, 28 HSi(OEt) 3 /Ti(O- i -Pr) 4 , 29 PhSiH 3 , 30 − 32 1,1,3,3-tetramethyldisiloxane (TMDS) with CuX 2 , 33 polymethylhydrosiloxane (PMHS), 34 , 35 1,3-diphenyldisiloxane (DPDS), 36 and (EtO) 2 MeSiH/(RO) 2 P(O)OH; 37 aluminum hydrides such as LiAlH 4 , 38 , 39 LiAlH 4 /CeCl 3 , 40 AlH 3 , 41 and HAl( i -Bu) 2 ; 42 low-valent metals such as SmI 2 /HMPA (hexamethylphosphoramide) 43 or Cp 2 TiCl 2 /Mg; 44 hydrocarbon/activated carbon; 45 and electrochemical reduction. 46 − 48 A mild iodine-catalyzed reduction of phosphine(V) oxides employing a sacrificial electron-rich phosphine was developed by Laven and Kullberg, 49 while Li et al 50 employed less expensive phosphite, although in both cases P (V) =O-containing contaminants must be removed from the final products. Thus, disadvantages of these procedures include harsh reaction conditions, toxic and/or highly reactive, potentially explosive reducing agents, narrow scope or undesirable side reactions, e.g.…”