Migration of phthalates, alkylphenols, bisphenol A and di(2-ethylhexyl)adipate from food packaging

Fasano, Evelina; Bono-Blay, Francisco; Cirillo, Teresa; Montuori, Paolo; Lacorte, Sı́lvia

doi:10.1016/j.foodcont.2012.03.005

Cited by 306 publications

(167 citation statements)

References 35 publications

(28 reference statements)

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“…They can deposit on unprocessed food ingredients such as crops and grapes through the deposition of dust and rain but can also directly migrate from food packaging into food and drinks (Fierens et al 2012a). In the case of beer and wine specifically, this can occur from plastic gaskets, lids and stoppers (Sendón et al 2012) as well as tetra pack, cans (Fasano et al 2012) and bottles depending on how the product is stored and sold. During the brewing/fermentation, maturation and bottling of beer and wine, the liquids are in contact with tubes and joints made from plastic.…”

Section: Introductionmentioning

confidence: 99%

Quantification of Six Phthalates and One Adipate in Luxembourgish Beer Using HS-SPME-GC/MS

2016

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A simple, low-cost and sensitive method for the determination of six phthalate acid esters (dimethyl phthalate, diethyl phthalate, dibutyl phthalate, benzyl butyl phthalate, bis(2-ethylhexyl) phthalate and dioctyl phthalate) and one adipate (bis(2-ethylhexyl) adipate) in beer has been developed using head-space solid-phase microextraction (HS-SPME) followed by gas chromatography coupled to mass spectrometry (GC/MS). SPME conditions were optimised, and optimum extraction parameters were found to be 95°C at 100 min, without addition of NaCl. Matrix interference was avoided by using a deuterated internal standard (ISTD). Limits of detection ranged from 0.006 to 0.590 μg/L. The method showed good linearity with coefficients of determination ranging from 0.963 to 0.999 and satisfactory accuracy (74-101 %) and repeatability (3.56-27.86 %) values. The method was applied to 15 samples of beer from Luxembourgish breweries, stored in different containers (can, glass and aluminium bottle), and phthalates were detected in all samples with concentrations as high as 61.56 μg/L for total phthalates. The exact origins of phthalates in beer were difficult to determine from the data in this study, though the brewing and bottling process seems to be a major contributor.

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Section: Introductionmentioning

confidence: 99%

Quantification of Six Phthalates and One Adipate in Luxembourgish Beer Using HS-SPME-GC/MS

2016

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“…Notably, their packaging materials (black PE, white PE, carton, and PET bottle) contained different levels of BPA (Table 3). It was reported that BPA can permeate into drinks from materials under condition of thermal treatment or microwave heating (Fasano et al 2012). In order to further verify the fact, we heated the container gradually to evaluate the dissolved BPA in three model beverages (water, milk, and alcohol) by the present method.…”

Section: Analysis Of Real Samplesmentioning

confidence: 87%

Ultrasensitive Fluorescence Immunoassay for Detection of Bisphenol A in Milk Products Using Functionalized Gold Nanoparticles as Probe

Zhang

et al. 2015

Food Anal. Methods

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An ultrasensitive fluorescence immunoassay was developed for detection of bisphenol A (BPA). Herein, thiolmodified single-strand DNA (SH-ssDNAs) and anti-BPA antibodies were simultaneously conjugated with gold nanoparticles (AuNPs), and the fluorescein isothiocyanate-labeled single-strand DNA was hybridized with SH-ssDNAs to form a dual-codified probe. In the presence of BPA, a competitive immunoreaction was conducted between BPA and BPA coating antigens immobilized on microplate for the anti-BPA antibodies of dual-codified probe. Then, in order to avoid the fluorescent signals quenched by AuNPs, restriction enzyme BamH І was employed to cut the fluorescent labels from immunocomplex, resulting in an increase of fluorescence emission. Under optimized conditions, the linear range for detection of BPA is from 1.0×10 −2 to 1.0×10 3 ng/L with a low limit of detection of 3.4×10 −3 ng/L. This method is of good sensibility, stability, and specificity, and it can be used to detect BPA in actual milk products and its migration from packaging materials into milk.

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“…Mass spectrometric detection can solve this problem because it is highly sensitive and structural information can be derived from the mass spectra. In previous studies, several chemicals and additives such as phthalates, alkylphenols, adipates and BisPhenol A (BPA) have been investigated in baverage, water and food packaging materials by using different techniques [7,8].…”

Section: David Publishingmentioning

confidence: 99%

Screening of Polymer Additives in Drinking Water Stored in PET Bottles by UHPLC-ESI-IT-TOF MS

Yılmaz¹,

Temel²

2016

JESE-A

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Migration of phthalates, alkylphenols, bisphenol A and di(2-ethylhexyl)adipate from food packaging

Cited by 306 publications

References 35 publications

Quantification of Six Phthalates and One Adipate in Luxembourgish Beer Using HS-SPME-GC/MS

Quantification of Six Phthalates and One Adipate in Luxembourgish Beer Using HS-SPME-GC/MS

Ultrasensitive Fluorescence Immunoassay for Detection of Bisphenol A in Milk Products Using Functionalized Gold Nanoparticles as Probe

Screening of Polymer Additives in Drinking Water Stored in PET Bottles by UHPLC-ESI-IT-TOF MS

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