“…Nanocolloidal lithography (NCL), [ 1–4 ] which uses nanoparticles of various sizes, shapes, and materials as an etching mask, enables simple and cost‐efficient fabrication of nanostructures in the fields of metamaterials, [ 5–7 ] solar cells, [ 8–10 ] displays, [ 11–13 ] sensors, [ 14–16 ] and on‐chip devices. [ 17–19 ] To improve the precision of colloidal lithography, such as the structural uniformity, [ 13,14,16,18 ] sidewall profile, [ 6,7,9,20 ] and step coverage, [ 8,11,12,21 ] high selectivity between the nanoparticles and targeted materials is critical and thus has been extensively studied. [ 5–22 ] However, for most nanoparticle etching masks (e.g., polystyrene, polyamide, and silica colloids), the etching selectivity is restricted to specific metals or dielectrics, requiring additional multiple or nonscalable fabrication steps hindering application of the advantages of the NCL process to multi‐material nanostructures.…”