Abstract:The amplitude of climatic change, as recorded in the benthic oxygen isotope record, has varied throughout geological time. During the late Pleistocene, changes in the atmospheric concentration of carbon dioxide (CO 2 ) are an important control on this amplitude of variability. The contribution of CO 2 to climate variability during the pre-Quaternary however is unknown. Here we present a new boron isotope-based CO 2 record for the transition into the middle Miocene Climatic Optimum (MCO) between 15.5 and 17 Myr… Show more
“…Although somewhat arbitrary, these values are within the range of published estimates. The 400 ppmv MMCO estimate represents a maximum rather than a mean (within the interval ~15-17 Ma) and is in favourable agreement with Foster et al (2012) and Tripati et al (2009), as well as with the most recent alkenone-and boron isotope-based p CO 2 reconstructions for the MMCO by Zhang et al (2013) and Greenop et al (2014). The 200 ppmv MMG estimate represents a minimum rather than a mean (within the interval ~12-15 Ma) and is in good agreement with Foster et al (2012) andPagani et al (2005).…”
“…Although somewhat arbitrary, these values are within the range of published estimates. The 400 ppmv MMCO estimate represents a maximum rather than a mean (within the interval ~15-17 Ma) and is in favourable agreement with Foster et al (2012) and Tripati et al (2009), as well as with the most recent alkenone-and boron isotope-based p CO 2 reconstructions for the MMCO by Zhang et al (2013) and Greenop et al (2014). The 200 ppmv MMG estimate represents a minimum rather than a mean (within the interval ~12-15 Ma) and is in good agreement with Foster et al (2012) andPagani et al (2005).…”
“…5 we show the new reference CO 2 results together with proxy data over three periods for which data are relatively abundant: the Late (Pagani et al, 1999(Pagani et al, , 2011Badger et al, 2013) are indicated by orange asterisks. Boron-isotope-based data (Pearson et al, 2009;Foster et al, 2012;Greenop et al, 2014;Martínez-Botí et al, 2015) are indicated by blue plus symbols. Stomata-based data (Van der Burgh et al, 1993;Kürschner, 1996;Kürschner et al, 2008;Retallack, 2009) Pliocene (3.5 to 2.5 Myr ago), the Middle Miocene (18 to 13 Myr ago), and the Early Oligocene (35 to 30 Myr ago).…”
Section: Comparison To Proxy Co 2 Datamentioning
confidence: 99%
“…Stomata-based data (Van der Burgh et al, 1993;Kürschner, 1996;Kürschner et al, 2008;Retallack, 2009) Pliocene (3.5 to 2.5 Myr ago), the Middle Miocene (18 to 13 Myr ago), and the Early Oligocene (35 to 30 Myr ago). The data are based on three important proxies (see also Beerling and Royer, 2011): alkenones (Pagani et al, 1999(Pagani et al, , 2011Badger et al, 2013), boron isotopes (Pearson et al, 2009;Foster et al, 2012;Greenop et al, 2014;Martínez-Botí et al, 2015), and stomata (Van der Burgh et al, 1993;Kürschner, 1996;Kürschner et al, 2008;Retallack, 2009). During the Late Pliocene, the simulated CO 2 is more variable than the alkenone data from Badger et al (2013) (Fig.…”
Abstract. Since the inception of the Antarctic ice sheet at the Eocene-Oligocene transition ( ∼ 34 Myr ago), land ice has played a crucial role in Earth's climate. Through feedbacks in the climate system, land ice variability modifies atmospheric temperature changes induced by orbital, topographical, and greenhouse gas variations. Quantification of these feedbacks on long timescales has hitherto scarcely been undertaken. In this study, we use a zonally averaged energy balance climate model bidirectionally coupled to a one-dimensional ice sheet model, capturing the ice-albedo and surface-height-temperature feedbacks. Potentially important transient changes in topographic boundary conditions by tectonics and erosion are not taken into account but are briefly discussed. The relative simplicity of the coupled model allows us to perform integrations over the past 38 Myr in a fully transient fashion using a benthic oxygen isotope record as forcing to inversely simulate CO 2 . Firstly, we find that the results of the simulations over the past 5 Myr are dependent on whether the model run is started at 5 or 38 Myr ago. This is because the relation between CO 2 and temperature is subject to hysteresis. When the climate cools from very high CO 2 levels, as in the longer transient 38 Myr run, temperatures in the lower CO 2 range of the past 5 Myr are higher than when the climate is initialised at low temperatures. Consequently, the modelled CO 2 concentrations depend on the initial state. Taking the realistic warm initialisation into account, we come to a best estimate of CO 2 , temperature, ice-volume-equivalent sea level, and benthic δ 18 O over the past 38 Myr. Secondly, we study the influence of ice sheets on the evolution of global temperature and polar amplification by comparing runs with ice sheet-climate interaction switched on and off. By passing only albedo or surface height changes to the climate model, we can distinguish the separate effects of the ice-albedo and surfaceheight-temperature feedbacks. We find that ice volume variability has a strong enhancing effect on atmospheric temperature changes, particularly in the regions where the ice sheets are located. As a result, polar amplification in the Northern Hemisphere decreases towards warmer climates as there is little land ice left to melt. Conversely, decay of the Antarctic ice sheet increases polar amplification in the Southern Hemisphere in the high-CO 2 regime. Our results also show that in cooler climates than the pre-industrial, the ice-albedo feedback predominates the surface-heighttemperature feedback, while in warmer climates they are more equal in strength.
“…Boron isotope measurements on fossil carbonates thus have the potential to constrain changes in pH and CO 2 over geological time (Pearson and Palmer 2000;Hönisch et al 2009;Rae et al 2014;Penman et al 2014;Greenop et al 2014;Martínez-Botí et al 2015a). The shells, or "tests", of foraminifera, which are single-celled protists, provide a convenient host for the d 11 B-pH proxy, being widely distributed throughout the world's oceans, relatively well-preserved in marine sediment cores, and having chemistry that closely reflects surrounding seawater conditions (Wefer et al 1999;Erez 2003).…”
The boron isotope composition of foraminifera provides a powerful tracer for CO 2 change over geological time. This proxy is based on the equilibrium of boron and its isotopes in seawater, which is a function of pH. However while the chemical principles underlying this proxy are well understood, its reliability has previously been questioned, due to the difficulty of boron isotope (d 11 B) analysis on foraminferal samples and questions regarding calibrations between d 11 B and pH. This chapter reviews the current state of the d 11 B-pH proxy in foraminfera, including the pioneering studies that established this proxy's potential, and the recent work that has improved understanding of boron isotope systematics in foraminifera and applied this tracer to the geological record. The theoretical background of the d 11 B-pH proxy is introduced, including an accurate formulation of the boron isotope mass balance equations. Sample preparation and analysis procedures are then reviewed, with discussion of sample cleaning, the potential influence of diagenesis, and the strengths and weaknesses of boron purification by column chromatography versus microsublimation, and analysis by NTIMS versus MC-ICPMS. The systematics of boron isotopes in foraminifera are discussed in detail, including results from benthic and planktic taxa, and models of boron incorporation, fractionation, and biomineralisation. Benthic taxa from the deep ocean have d 11 B within error of borate ion at seawater pH. This is most easily explained by simple incorporation of borate ion at the pH of seawater. Planktic foraminifera have d 11 B close to borate ion, but with minor offsets. These may be driven by physiological influences on the Electronic supplementary material The online version of this chapter
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