Mid-wave infrared planar optical device via femtosecond laser ablation on a sulfur-based polymeric glass surface

Liu, Feng; Zhang, Liang; Cheng, Hao; Liu, Sheng; Shan, Mingguang; Jin, Chuan; Zhu, Xiangping; Zhao, Jianlin

doi:10.1364/ome.459018

“…These capabilities complement recent innovations in making complex structures on polysulfide surfaces using high-powered pulsed lasers, electron beam lithography, plasma etching, and thermal nanoimprint lithography-all of which have proven useful for innovative optics applications. [27][28][29][30] The present study, in contrast, is distinguished in the variety of modifications (spikes, lines, pits, channels and holes) that can be installed directly on the featured polymers using low-power laser light.…”

Section: Introductionmentioning

confidence: 99%

Modification of Polysulfide Surfaces with Low‐Power Lasers

Mann,

Lisboa,

Tonkin

et al. 2024

Angewandte Chemie

0

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The modification of polymer surfaces using laser light is important for many applications in the nano‐, bio‐ and chemical sciences. Such capabilities have supported advances in biomedical devices, electronics, information storage, microfluidics, and other applications. In most cases, these modifications require high power lasers that are expensive and require specialized equipment and facilities to minimize risk of hazardous radiation. Additionally, polymer systems that can be easily modified by lasers are often complex and costly to prepare. In this report, these challenges are addressed with the discovery of low‐cost sulfur copolymers that can be rapidly modified with lasers emitting low‐power infrared and visible light. The featured copolymers are made from elemental sulfur and either cyclopentadiene or dicyclopentadiene. Using a suite of lasers with discreet wavelengths (532, 638 and 786 nm) and powers, a variety of surface modifications could be made on the polymers such as controlled swelling or etching via ablation. The facile synthesis and laser modification of these polymer systems were exploited in applications such as direct laser lithography and erasable information storage.

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Modification of Polysulfide Surfaces with Low‐Power Lasers

Mann,

Lisboa,

Tonkin

et al. 2024

Angew Chem Int Ed

2

0

View full text Add to dashboard Cite

The modification of polymer surfaces using laser light is important for many applications in the nano‐, bio‐ and chemical sciences. Such capabilities have supported advances in biomedical devices, electronics, information storage, microfluidics, and other applications. In most cases, these modifications require high power lasers that are expensive and require specialized equipment and facilities to minimize risk of hazardous radiation. Additionally, polymer systems that can be easily modified by lasers are often complex and costly to prepare. In this report, these challenges are addressed with the discovery of low‐cost sulfur copolymers that can be rapidly modified with lasers emitting low‐power infrared and visible light. The featured copolymers are made from elemental sulfur and either cyclopentadiene or dicyclopentadiene. Using a suite of lasers with discreet wavelengths (532, 638 and 786 nm) and powers, a variety of surface modifications could be made on the polymers such as controlled swelling or etching via ablation. The facile synthesis and laser modification of these polymer systems were exploited in applications such as direct laser lithography and erasable information storage.

show abstract