The radio source 1146+596 is hosted by an elliptical/S0 galaxy NGC 3894, with a low-luminosity active nucleus. The radio structure is compact, suggesting a very young age of the jets in the system. Recently, the source has been confirmed as a high-energy (HE, > 0.1 GeV) γ-ray emitter, in the most recent accumulation of the Fermi Large Area Telescope (LAT) data. Here we report on the analysis of the archival Chandra X-ray Observatory data for the central part of the galaxy, consisting of a single 40 ksec-long exposure. We have found that the core spectrum is best fitted by a combination of an ionized thermal plasma with the temperature of 0.8 keV, and a moderately absorbed power-law component (photon index Γ 1.4 ± 0.4, hydrogen column density N H /10 22 cm −2 2.4 ± 0.7). We have also detected the iron Kα line at 6.47±0.07 keV, with a large equivalent width of EW 1 keV. Based on the simulations of the Chandra's Point Spread Function (PSF), we have concluded that, while the soft thermal component is extended on the scale of the galaxy host, the hard X-ray emission within the narrow photon energy range 6.0-7.0 keV originates within the unresolved core (effectively the central < 51.2 kpc radius). The line is therefore indicative of the X-ray reflection from a cold neutral gas in the central regions of NGC 3894. We discuss the implications of our findings in the context of the X-ray Baldwin effect, and the overall energetic of the system. We note that NGC 3894 becomes the first HE γ-ray source with the detected Kα iron line.