Abstract:We present the microwave spectra of the fourth molecule containing the four-fold rotor-SF 5 , phenylsulfur pentafluoride, cC 6 H 5-SF 4-F (PhSPF). The first three molecules in this series were vinylsulfur pentafluoride (VSPF), propen-1ylsulfur pentafluoride (PSPF) and buten-1-ylsulfur pentafluoride (BSPF). VSPF exhibited splitting into the A, E, and B torsional states with 10's of MHz between the torsional transitions. PSPF exhibited the torsional splitting with 10's of kHz between transitions. BSPF exhibited … Show more
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