This paper shows that the accuracy of azimuth angle measurement for an interferometric localization system used to locate tags in its Line-of-Sight (LoS) can be improved by exploiting Impulse Radio-Ultra WideBand (IR-UWB) signals and without increasing the frequency bandwidth. This solution uses a Phase Correlation (PC) method, initially applied for Continuous Wave (CW) signals, adapted for Ultra WideBand (UWB) pulse signals. The obtained results are compared to those computed by a classical Energy Detection (ED) method where it becomes impossible to estimate azimuth angles for tag positions close to the orthogonal centered axis of the localization system baseline.