Abstract:Metamaterials (MTMs) are artificial materials composed of subwavelength particles, which are engineered to achieve various electromagnetic (EM) responses. Since the first practical realization and experimental verification of MTMs by Pendry et al. in the late 1990s, great efforts have been made in theoretical study as well as practical utilizations. Among them, the effective medium theory provides a basis for the description as well as an accurate method for the design of MTMs, and leads to the development of … Show more
“…As an extrusion printing technology, DIW facilitates the formation of a continuous conductance path inside an entire 3D architecture and meets the prerequisite of high electrical conductivity for EMI shielding [26,27]. The flexibility of design makes it possible to prepare periodic unit structures on the basis of electromagnetic theories [28,29]. Wang et al [30] prepared 3D core-shell structured liquid metal/elastomer composites with adjustable shielding efficiency by varying printing layers.…”
Highlights
3D printing of MXene frames with tunable electromagnetic interference shielding efficiency is demonstrated.
Highly conductive MXene frames are reinforced by cross-linking with aluminum ions.
Electromagnetic wave is visualized by electromagnetic-thermochromic MXene patterns.
Abstract
The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference (EMI) shielding materials to assure the normal operation of their closely assembled components. However, the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency. Herein, we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications. The as-printed frames are reinforced by immersing in AlCl3/HCl solution to remove the electrically insulating AlOOH nanoparticles, as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions. After freeze-drying, the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25â80Â dB with the highest electrical conductivity of 5323 S mâ1. Furthermore, an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern, and its color can be changed from blue to red under the high-intensity electromagnetic irradiation. This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves.
“…As an extrusion printing technology, DIW facilitates the formation of a continuous conductance path inside an entire 3D architecture and meets the prerequisite of high electrical conductivity for EMI shielding [26,27]. The flexibility of design makes it possible to prepare periodic unit structures on the basis of electromagnetic theories [28,29]. Wang et al [30] prepared 3D core-shell structured liquid metal/elastomer composites with adjustable shielding efficiency by varying printing layers.…”
Highlights
3D printing of MXene frames with tunable electromagnetic interference shielding efficiency is demonstrated.
Highly conductive MXene frames are reinforced by cross-linking with aluminum ions.
Electromagnetic wave is visualized by electromagnetic-thermochromic MXene patterns.
Abstract
The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference (EMI) shielding materials to assure the normal operation of their closely assembled components. However, the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency. Herein, we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications. The as-printed frames are reinforced by immersing in AlCl3/HCl solution to remove the electrically insulating AlOOH nanoparticles, as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions. After freeze-drying, the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25â80Â dB with the highest electrical conductivity of 5323 S mâ1. Furthermore, an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern, and its color can be changed from blue to red under the high-intensity electromagnetic irradiation. This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves.
“…This technology has been applied to the manufacture of metamaterials and artificial electromagnetic (EM) medium [24][25][26]. The GRIN lens manufacturing at the millimetre level has now been realized [27,28].…”
Based on transformation optics, a strategy is proposed to expose the inner one-dimensional space of a wave field inside a beam volume to the surface of the propagation medium and extend the space from one-dimensional to two-dimensional, allowing the corresponding field distribution to be detected directly and more subtly, which is important in optical signal processing. The method is applied to the quadratic graded index lens to construct a new graded index lens, and its enhanced chirpyness detection ability is demonstrated by numerical simulation.
“…EMs operate at several different frequencies depending on the operating wavelength and target application. Thus, EMs are comprised of several types of metamaterials that apply to specific wavelengths including radio waves, 41 microwaves, 42 terahertz, 43,44 infrared, 45 and visible light (i.e., photonic metamaterials). 46,47 EMs are made possible through the manipulation of Maxwell's equations (Table 1).…”
We place metamaterials in the context of underpinning physical phenomena, including negative refraction, bandgaps, wave focusing, and negative Poissonâs ratio. The designs, mechanisms, governing equations, and effective parameters are discussed.
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