A very cold and collisional hot-filament discharge plasma is created in a vacuum chamber with an inner wall cooled by liquid nitrogen. The inner chamber ͑16.5 cm diameterϫ 30 cm͒ has two negatively biased tungsten filaments for plasma generation and a Langmuir probe on axis for diagnostic measurements. With the wall at 140 K, 0.5-16 mA filament emission, and 1.6 mTorr carbon monoxide as the working gas, probe data give electron temperatures of 17-28 meV ͑197-325 K͒ with corresponding densities of 10 8 -10 9 cm −3 . With He, Ar, H 2 , and N 2 at 140 K, the electron temperatures are Ͼ500 K. The lower electron temperature with CO is attributed to the asymmetric CO molecule having a larger cross section for electron excitation of rotational modes as a consequence of its dipole moment.