Microwave‐assisted Rhodium(I)‐Catalyzed C8‐Regioselective C−H Alkenylation and Arylation of 1,2,3,4‐Tetrahydroquinolines with Alkenyl and Aryl Carboxylic Acids
Haoqiang Zhao,
Qi Zeng,
Ji Yang
et al.
Abstract:Rh(I)‐catalyzed C8‐selective C–H alkenylation and arylation of 1,2,3,4‐tetrahydroquinolines with readily available and inexpensive alkenyl and aryl carboxylic acids under microwave assistance have been realized. Using [Rh(CO)2(acac)] as the catalyst and Piv2O as the acid activator, various 1,2,3,4‐tetrahydroquinolines undergo smooth C8‐selective decarbonylative C–H alkenylation with a wide range of alkenyl carboxylic acids, affording the C8‐alkenylated 1,2,3,4‐tetrahydroquinolines with high efficiency and wide… Show more
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