Microwave-assisted MOF@biomass layered nanomaterials: Characterization and applications in wastewater treatment

Fernández-Andrade, Kevin Jhon; Fernández-Andrade, Alex; Zambrano-Intriago, Luis Ángel; Arteaga-Pérez, Luis E.; Alejandro-Martin, Serguei; Baquerizo-Crespo, Ricardo José; Luque, Rafael; Rodríguez-Díaz, Joan Manuel

doi:10.1016/j.chemosphere.2022.137664

Cited by 16 publications

(4 citation statements)

References 24 publications

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“…This was substantiated by the high enthalpy value (129 kJ mol −1 ) of the process, attributed to the interaction between the Al 3+ of the octahedral corner of the MOF and the phosphonate group in the glyphosate molecule. 16 Conversely, Yan et al 44 synthesized a MIL-53(Fe)-based material in As 5+ ADS and the mechanism suggested chemisorption through chelation between MOF nodes (metal) and the adsorbate (it appears that the metal cluster within the crystalline MOF is responsible for the chemical ADS). Hence, this study underscores the importance of enhancing the efficiency of MOF-biomass functionalization.…”

Section: Resultsmentioning

confidence: 99%

“…[11][12][13] Our recent research focuses on enhancing the structure and applications of adsorption through the functionalization of residual biomasses of lignocellulosic origin with MOFs. [14][15][16] This innovative approach offers several advantages, addressing challenges presented by both materials individually improved adsorption capacity in biomass and simplified recovery of MOFs after use. The resulting hybrid material exhibits significant technical and economic potential compared to pure MOF powders, making it an attractive option for industrial applications.…”

Section: Introductionmentioning

confidence: 99%

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Biomass@MOF nanohybrid materials for competitive drug adsorption: analysis by conventional macroscopic models and statistical physical models

Rivadeneira-Mendoza,

Quiroz-Fernández,

da Silva

et al. 2024

Environ. Sci.: Nano

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Biomass@MOF nanohybrid materials for competitive drug adsorption: analysis by conventional macroscopic models and statistical physical models

Rivadeneira-Mendoza,

Quiroz-Fernández,

da Silva

et al. 2024

Environ. Sci.: Nano

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“…The purpose of using the microwave method is to provide optimal conditions for forming MOF nanostructures with desirable properties such as small particle size distribution, desirable thermal stability, and good textural properties. The mechanism of formation of MOF nanostructures by using a microwave-assisted method is developed in this study based on previous literature ( Choi et al, 2008 ; Couzon et al, 2022 ; Fernández-Andrade et al, 2023 ).…”

Section: Discussionmentioning

confidence: 99%

Microwave-assisted synthesis of novel Ti/BTB-MOFs as porous anticancer and antibacterial agents

Altharawi,

Alqahtani,

Aldakhil

et al. 2024

Front. Chem.

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Nano compounds, especially metal-organic frameworks (MOFs), have significant properties. Among the most important properties of these compounds, which depend on their specific surface area and porosity, are biological properties, such as anticancer and antibacterial properties. In this study, a new titanium/BTB metal-organic framework (Ti/BTB-MOF) was synthesized by using titanium nitrate and 1,3,5-Tris(4-carboxyphenyl)benzene (BTB) under microwave radiation. The structure of the synthesized Ti/BTB-MOF was characterized and confirmed using X-ray diffraction (XRD) patterns, X-ray photoelectron spectroscopy (XPS) analysis, Fourier transform infrared (FT-IR) spectra, energy-dispersive X-ray (EDAX) analysis mapping, scanning electron microscope (SEM) images, thermogravimetric analysis (TGA) curves, and Brunauer–Emmett–Teller (BET) analysis. The in vitro anticancer properties of Ti/BTB-MOF were evaluated using the MTT method against MG-63/bone cancer cells and A-431/skin cancer cells. The in vitro antibacterial activity was tested using the Clinical and Laboratory Standards Institute (CLSI) guidelines. In the anticancer activity, IC50 (half-maximal inhibitory concentration) values of 152 μg/mL and 201 μg/mL for MG-63/bone cancer cells and A-431/skin cancer cells, respectively, were observed. In the antibacterial activity, minimum inhibitory concentrations (MICs) of 2–64 μg/mL were observed against studied pathogenic strains. The antimicrobial activity of Ti/BTB-MOF was higher than that of penicillin and gentamicin. Therefore, the synthesized Ti/BTB-MOF could be introduced as a suitable bioactive candidate.

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“…This method significantly reduces the reaction time and enhances the overall yield of the MOF synthesis process. [ 25 ] Consequently, microwave‐assisted synthesis presents a promising avenue for efficiently and rapidly synthesizing MOFs, thereby contributing to progress in various fields. [ 26 ] This approach underscores the potential to exploit the inherent characteristics of MOFs while benefiting from expedited synthesis methods.…”

Section: Properties and Synthesis Techniques Of Mofsmentioning

confidence: 99%

Metal–Organic Framework‐Integrated Composites for Bone Tissue Regeneration

Mi,

Xiong,

Zhao

et al. 2023

Adv Funct Materials

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Metal–organic frameworks (MOFs) exhibit exceptional characteristics, including high porosity and adjustable properties, rendering them highly suitable for biomedical applications. Recently, researchers have directed their attention toward the integration of MOFs into composites for bone tissue regeneration (BTE), presenting distinct advantages over conventional substitutes. In this comprehensive review, the authors delve into the latest advancements concerning MOF‐integrated composites for BTE. This exploration encompasses an examination of the properties of MOFs and the various synthesis techniques employed to fabricate these materials. Furthermore, the diverse applications of MOF‐integrated composites in BTE are investigated, encompassing areas such as antibacterial properties, osteogenic differentiation, angiogenesis, and immunomodulation. By providing a comprehensive overview of the ongoing research on MOF‐integrated composites for BTE, this study holds the promise of yielding innovative solutions within the realm of orthopedics.

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Microwave-assisted MOF@biomass layered nanomaterials: Characterization and applications in wastewater treatment

Cited by 16 publications

References 24 publications

Biomass@MOF nanohybrid materials for competitive drug adsorption: analysis by conventional macroscopic models and statistical physical models

Biomass@MOF nanohybrid materials for competitive drug adsorption: analysis by conventional macroscopic models and statistical physical models

Microwave-assisted synthesis of novel Ti/BTB-MOFs as porous anticancer and antibacterial agents

Metal–Organic Framework‐Integrated Composites for Bone Tissue Regeneration

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