Microwave assisted hydrothermal synthesis of a novel CuI-sulfate-pyrazine MOF

Fabrication of nanosheets of a fluorescent metal–organic framework [Zn(BDC)(H2O)]n (BDC=1,4-benzenedicarboxylate): Ultrasonic synthesis and sensing of ethylamine

“…several days for hydrothermal and solvothermal methods, or several weeks for diffusion method) and have to be performed at high reaction temperature (usually 373-523 K) and pressure (1-10 MPa) in many cases. Recently, a highly efficient route to MOFs has been developed through a microwave assisted hydrothermal method, but the reaction is still carried out at high reaction temperature and pressure [8,9]. Furthermore, compared with the rapid developments and numerous studies on their applications in selective adsorption, molecular exchange and separation, especially the latest howling successes in hydrogen storage [10][11][12], application of MOFs in sensor technology remains largely unexplored [13,14].…”

One Decade of Microwave‐Assisted Polymerizations: Quo vadis?

“…2 ], under microwave irradiation was also reported by Zamora and coworkers. [212] Notably, microwave irradiation provided the reducing power conditions to form the coordination polymer from Cu(II)SO 4 as reactant; nitrogenrich ligands are well known to serve as reducing agents for this reaction at high temperatures. The reduction of copper(II) to copper(I) under microwave irradiation in the presence of 2,2 0 -dipyridylsulfide was also reported.…”

Microwave-Assisted Synthesis of Coordination and Organometallic Compounds

“…The availability of this class of complexes in a few minutes offers the possibility of a combinatorial approach for the preparation of libraries of homologous compounds of potential interest for large-scale screening studies. MWAS of [Cu 2 (pz) 2 (SO 4 )(H 2 O) 2 ] n (pz = pyrazine) produced monocrystal suitable for X-ray diffraction studies, reducing reaction time and with higher yield than the classical hydrothermal procedures (Amo-Ochoa et al, 2007). The iridium complexes, obtained by cyclometalation of 5-(3-cyanophenyl)-2,3-diphenylpyrazine by 0.22 g of IrCl 3 .…”