Microstructure and Phase Composition of Cold Isostatically Pressed and Pressureless Sintered Silicon Nitride

Lukianova, O.A.; Krasilnikov, V. V.; Parkhomenko, A. A.; Сирота, В. В.

doi:10.1186/s11671-016-1365-1

Cited by 21 publications

(8 citation statements)

References 16 publications

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“…The results obtained are extremely satisfactory, when compared with those of literature-where the liquid phase sintering technique is adopted in the latter: as examples, Matovic Bocanegra-Bernal [29] obtained the density ranges from 86 to 100% after several sintering techniques, with temperatures between 1500 and 1825°C; Huang et al [30], using a pulsed electric current sintering, obtained full density at 1650°C [18].…”

Section: Characterization Of Hpht Sintered Samplessupporting

confidence: 52%

“…The results of fracture toughness indicate that the ceramics present high K IC between 8.5 and 10 MPa m 1/2 , even without the presence of intergranular phase, and motivate its use as a cutting tool. Tatli et al [18], when studying sintering-aided Si 3 N 4 , found fracture toughness ranging from 4.2 to 5.3 MPa m 1/2 . According to data reported by Tapasztó et al [33], the fracture toughness values vary between 2 and 5 MPa m 1/2 .…”

Section: Mechanical Propertiesmentioning

confidence: 99%

“…Sintering additives, such as Y 2 O 3 (or mixture of rare earth oxides) and Al 2 O 3 , are usually mixed witha-Si 3 N 4 particles which possess surface layers of silica. The rare earth oxides and Al 2 O 3 react with this silica and with some of the silicon nitride itself at sintering temperatures to form liquid oxynitride, which promotes densification by solution-precipitation [7,8,17,18].…”

Section: Introductionmentioning

confidence: 99%

“…Among the sintering techniques for silicon nitride, liquid phase sintering has been used to obtain Si 3 N 4 with high bending strength, fracture toughness and high hardness. This process is carried out at 1750-1900°C under a nitrogen atmosphere (0.1-10 MPa) [1,2,10,[16][17][18].…”

Section: Introductionmentioning

confidence: 99%

“…Due to the potential use of this ceramic, several liquid phase sintering processes have been studied such as uniaxial hot pressing (HP) [18][19][20], using pressures up to 100 MPa, hot isostatic pressing (HIP), using pressures up to 400 MPa [21], microwave sintering [22] and spark plasma sintering (SPS) [23], among others. As common feature, all these techniques reveal the presence of residual intergranular phase among the b-Si 3 N 4 grains.…”

Section: Introductionmentioning

confidence: 99%

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HPHT sintering of binderless Si3N4: structure, microstructure, mechanical properties and machining behavior

Filgueira

Nascimento

Oliveira

et al. 2018

J Braz. Soc. Mech. Sci. Eng.

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Silicon nitride (Si 3 N 4) is widely used in the manufacture of cutting tools due to the combination of properties such as high hardness, fracture toughness and wear resistance. This ceramic is usually sintered by liquid phase, causing the reduction of thermo-mechanical properties. This work investigated the sintering of pure (binderless) Si 3 N 4 tools by a high pressure and high-temperature (HPHT) technology. Sub-micrometric a-Si 3 N 4 powder was hot-pressed at 1700°C for 3 min, using extreme pressures of 5, 6 or 7 GPa. The sintered samples were characterized by XRD and atomic force microscopy (AFM); hardness and fracture toughness were measured by the indentation fracture method (IF). Preliminary machining tests with binderless-Si 3 N 4 tools were performed using AISI 4140 hardened steel. Commercial TiN-coated hard metal insert was used as a comparative tool material. Turning tests were carried out using coolant/lubricant, cutting time of 12 min, cutting speed of 150 m/min, cutting depth of 0.3 mm and feed of 0.11 mm/rev. The results showed the presence of a-Si 3 N 4 and b-Si 3 N 4 crystalline phases after sintering, indicating partial a ? b phase transformation, with elongated b-Si 3 N 4 grain. The relative density after sintering was near 90-97%. The best results for the mechanical properties were hardness of 21 GPa and fracture toughness of 8.9 MPa m 1/2. The machining results indicated an improvement on surface quality when using Si 3 N 4 ceramic tool. The flank wear of the hard metal insert was 0.7 mm, while the wear of binderless Si 3 N 4 insert was substantially lower, 0.1 mm. The roughness (R a) measured in AISI 4140 steel was 17.6 lm (HPHT Si 3 N 4 insert) and 19.7 lm (TiN-coated hard metal insert), after machining tests. Keywords Si 3 N 4 ceramics Á High-pressure and high-temperature (HPHT) Á Mechanical properties Á Machining

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Section: Characterization Of Hpht Sintered Samplessupporting

confidence: 52%

Section: Mechanical Propertiesmentioning

confidence: 99%