Microstructure and Mössbauer studies on magnetostrictive Tb 0.3 Dy 0.7 Fe 1.95−x Nb x (x = 0, 0.025, 0.05 and 0.075) J. Arout Chelvane · Mithun Palit · S. Pandian · M. Manivel Raja · V. ChandrasekaranAbstract Alloys of Dy 0.7 Tb 0.3 Fe 1.95−x Nb x (x = 0, 0.025, 0.05 and 0.075) were prepared in vacuum employing an induction furnace and investigated for the magnetic properties and microstructural features. A significant improvement in the magnetostriction has been obtained for the alloys containing Nb as compared to that of the parent alloy (x = 0). The Curie temperature and the Fe hyperfine field of the (Tb,Dy)Fe 2 phase are nearly invariant despite Nb addition to the parent alloy. The microstructural features, on the other hand, indicated that another Laves phase, NbFe 2 is formed as the primary phase at the expense of the undesired (Tb,Dy)Fe 3 phase. From the Mössbauer studies also the formation of NbFe 2 phase has been evidenced.