“…T he Co-HHN andP d-Co-HHN sensors showed sensitivea nd selective detectiono f methylbenzenes with negligible interference from other gases, whereas neither selectivity towards as pecific gas nor ah igh gas response was attained with the Co-CS and Co-HS sensors. Note that the response and selectivity of even the undoped Co-HHN sensor to xylene and toluene at 250 and 300 8Ci nt his study are the highest to have been reported in the literature for pure andc atalyst-loaded oxide semiconductor sensors using SnO 2 , [9,[24][25][26][27] ZnO, [28,29] Fe 2 O 3 , [30,31] WO 3 , [32] TiO 2 , [11] Co 3 O 4 , [12,[33][34][35] Pd-SnO 2 , [10] ZnSnO 3 , [36] Ag-ZnO-SnO 2 , [37] NiO-SnO 2 , [38] TiO 2 -ZnO, [39] Co-ZnO, [40] Cr-NiO, [14] Cr-Co 3 O 4 , [41] Sn-ZnO, [42] Mo-ZnO, [43] TiO 2 -Fe 2 O 3 , [44] Pd-WO 3 , [45] SnO 2 /Fe 2 O 3 , [46] Sb-ZnO, [47] andI n-ZnO [48] (Figure 4e organic sacrificial templates by electrostatic cross-linking between amphiphilic l-(+ +)-lysine molecules in the initial stage of the reaction, followed by the nucleation and growth of cobalt precursors without preferred orientation at the surfaces of the sacrificial templates in the later stages of the reaction. The addition of 5vol %w ater to the stock solution dramatically changed the morphology of Co 3 O 4 from hollow structures with smooth surfaces to hollow hierarchical nanostructures assembled from crystalline nanosheets.…”