Microstructural response and wear behaviour of Ti-6Al-4V impregnated with Ni/Al2O3 + TiO2 nanostructured coating using an electric arc

Abstract

Titanium alloys are known for their excellent corrosion resistance; however, low surface hardness results in poor wear resistance, which limits its potential application. This study employs a novel two-step process to embed a hard Ni coating containing a mixture of nanosized particles (Al2O3 and TiO2) into the surface of the Ti-6Al-4V alloy using an electric arc produced during the inert tungsten gas welding process. The surface of the sample was evaluated using Vickers Microhardness, Scanning electron microscopy, Energy dispersive spectroscopy and pin-on-plate wear testing. Microstructural analysis showed that impregnating the titanium surface with Ni/(Al2O3 and TiO2) nanomaterials resulted in the formation of a hard martensitic structure to a depth of approximately 2 mm below the surface. The changes observed are driven by modification of the surface chemistry and the presence of nickel, causing grain size reduction, solid solution strengthening and dispersion strengthening of the treated layer by the nanoparticles. The hardness of the treated layer increased by more than 180% when 40 nm Al2O3 and 30 nm TiO2 particles were embedded into the surface. Similarly, the wear resistance of the treated surface improved by 100%.

Titanium Nitride Coatings on CoCrMo and Ti6Al4V Alloys: Effects on Wear and Ion Release

“…However, not all patients can tolerate these alloys, and their use has been linked to issues like host bone resorption [24][25][26]. Coatings, particularly those developed through micro-arc oxidation, have shown promise in improving not only the osteogenic, antibacterial, and anti-inflammatory properties of metal implants [27][28][29][30], but also their wear properties [29,31,32], underscoring the significance of advanced coating technologies in addressing these challenges.…”