Abstract:Copper‐mediated atom transfer radical polymerization (ATRP) is versatile for living polymerizations of a wide range of monomers, but ATRP of vinyl acetate (VAc) remains challenging due to the low homolytic cleavage activity of the carbon‐halide bond of the dormant poly(vinyl acetate) (PVAc) chains and the high reactivity of growing PVAc radicals. Therefore, all the reported highly active copper‐based catalysts are inactive in ATRP of VAc. Herein, we report the first copper‐catalyst mediated ATRP of VAc using C… Show more
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