For a given cloud, whether the cloud top is predominately made up of ice crystals or supercooled liquid droplets plays a large role in the clouds overall radiative effects. This study uses collocated airborne radar, lidar, and thermodynamic data from 12 high-altitude flight legs during the Southern Ocean Clouds, Radiation, Aerosol Transport Experimental Study (SOCRATES) to characterize Southern Ocean (SO) cold sector cloud top phase (i.e., within 96 m of top) as a function of cloud top temperature (CTT). A training data set was developed to create probabilistic phase classifications based on High Spectral Resolution Lidar data and Cloud Radar data. These classifications were then used to identify dominant cloud top phase. Case studies are presented illustrating examples of supercooled liquid water at cloud top at different CTT ranges over the SO (−3°C < CTTs < −28°C). During SOCRATES, 67.4% of sampled cloud top had CTTs less than 0°C. Of the subfreezing cloud tops sampled, 91.7% had supercooled liquid water present in the top 96 m and 74.9% were classified entirely as liquid-bearing. Liquid-bearing cloud tops were found at CTTs as cold as −30°C. Horizontal cloud extent was also determined as a function of median cloud top height. Plain Language Summary Low-level clouds over the Southern Ocean have a large effect on the region's radiation budget. The radiation budget is strongly influenced by the phase (liquid or ice) of cloud tops, which is where most solar radiation is reflected, and most infrared radiation is radiated to space. For this reason, identifying the phase of cloud tops is important. In this study, airborne radar, lidar, and temperature data from 12 high-altitude flight legs during the Southern Ocean Clouds, Radiation, Aerosol Transport Experimental Study (SOCRATES) are used to characterize Southern Ocean cloud top phase as a function of cloud top temperature. The results show that liquid is the dominant phase present in clouds over the Southern Ocean, with liquid present at cloud top temperatures as cold as −30°C.