“…With the development of aerospace, superconducting magnets, and nuclear fusion power research, the availability of thermometers for cryogenic temperatures has become more important. , Recently, several ratiometric thermometers based on lanthanoid metal–organic frameworks (MOFs) have been reported containing a mixture of lanthanide ions, mainly Eu III and Tb III . ,,− However, the lack of sensitivity at cryogenic temperatures limits their application. Extending the sensing temperature range to below 50 K is of great value for both cryogenic research and industrial applications, e.g., energy and space exploration.…”