“…Thermoelectric (TE) power generation devices realize the direct conversion between heat and electricity, presenting many indispensable applications in special scenarios 1-3 such as energy supply of space explores 4 , massive sensors for the internet [5][6] , and waste heat recovery from power plants, car exhaust, or fossil fuels [7][8] . In addition, the cooling function of TE devices shows great potential because of the precise and fast micro-zone temperature control [9][10] , especially for the thermal management of microchips [11][12] . Very recently, high-efficiency TE devices assembled with state-of-the-art TE materials are frequently emerged in the prestigious news, such as PbTe 13 , half-Heusler 14 , GeTe 15 , SnSe 16 , Cu 2 Se 17 , AgSbTe 2 2 , Mg 3 Sb 2 9 , and so on.…”