“…Recent studies have used variations in δ 44 Ca and δ 24 Mg values to constrain the extent of rock‐buffered and fluid‐buffered systems in early marine diagenesis, and then applied this information to the interpretation of the stratigraphic variability of other geochemical signatures (for example, δ 13 C carb and δ 7 Li; Higgins et al ., 2018; Crockford et al ., 2020; Fantle et al ., 2020; Ahm et al ., 2021; Murphy et al ., 2022). However, in ancient successions, late diagenetic processes, such as hydrothermal fluids migrating along fractures, can also significantly alter the δ 44 Ca and δ 24 Mg values of carbonates (Walter et al ., 2015; Riechelmann et al ., 2020; Kimmig et al ., 2021), overprinting the signal of early marine diagenesis. A recent investigation, using a combination of multiple geochemical techniques (Δ 47 , δ 44 Ca, δ 24 Mg and δ 34 S values), has shown the different responses of diverse geochemical proxies in the Bahamas (Murray et al ., 2021).…”