Mg/Al complex oxides-A new type of solid basic catalyst for epoxidation

Abstract

Hydrotalcites known as anionic clays are found in nature. Hydrotalcites, hydrotalcite-like compounds, and calcined hydrotalcites (as mixed or complex oxides) as highly active, selective catalysts play an important role in many base/catalyzed reactions. Mg/Al hydrotalcite (MAH) as precursor was used to prepare Mg/Al metal complex oxides (MAO), used as epoxidation catalysts in the current research. In this paper, some primary physical and catalytic properties of MAH and MAO were investigated. The results indicated that the qualified MAH (Mg/Al mol ratio of 3) can be achieved when the suspension was crystallized under 80°C for 16h, and after being filtered, dried at 100 °C for 5h in a oven. MAO was prepared by calcining MAH for 4h in a muffle furnace, and calcination temperature was determined to be 500 °C by a differential scanning calorimeter (DSC). Crystal structure and parameters of MAH and MAO were characterized by X/ray diffraction (XRD), good crystal structure was observed and typical peaks of MAH were detected when 2θ was at 11.5 (003), 23.0 (006), 35.0 (009), and 61.0 (110), respectively. The morphology of calcined precursor, i.e. MAO, was investigated with scanning electron microscopy (SEM); the finer lamellar structure and smaller average size of 3μm was observed. Molding research was performed and confirmed by SEM, the results indicated that the surface bulge and cavity with size of several micrometers were increased, which simultaneously suggested the increasing of specific surface area. The catalytic activity of molding MAO was finally examined by using octanol as starting reagent and ethylene oxide as reactant, and narrower molecular distribution was observed comparing with the traditional catalyst-KOH

Kinetic Studies and Reaction Network in the Epoxidation of Styrene Catalyzed by the Temperature-Controlled Phase-Transfer Catalyst [(C18H37)2(CH3)2N]7[PW11O39]

“…Due to the wide applications of styrene oxide, researchers have made efforts to find catalysts that could catalyze the epoxidation reaction to produce styrene oxide. Various catalysts such as metal complexes, − silicates, − molecular sieve, − and poly­(oxometalates) − have been reported for the H 2 O 2 -based catalytic epoxidation. Homogeneous catalysts exhibit high catalytic activity but have difficulties in recycling and reuse .…”