Mevalonic acid and delpheline biosynthesis

Herbert, E. J.; Kirby, G. W.

doi:10.1016/s0040-4039(01)90861-5

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Biosynthetic Evidence2

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2012

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Cited by 11 publications

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“…The expected pathway through geranyl pyrophosphate, farnesyl pyrophosphate and geranylgeraniol pyrophosphate has been demonstrated (2) for the diterpenoid fungal metabolite, rosenonolactone (40). It is not our intention to discuss in detail these general aspects of terpenoid biochemistry but to concentrate on the diterpenoid substances.…”

Section: Biosynthetic Evidencementioning

confidence: 99%

“…Work with plant systems has been hampered by low incorporations (34) and there are even reports (40,47) of negative incorporations of mevalonate into compounds such as delpheline and sclareol which are clearly diterpenoid. Work with plant systems has been hampered by low incorporations (34) and there are even reports (40,47) of negative incorporations of mevalonate into compounds such as delpheline and sclareol which are clearly diterpenoid.…”

Section: Biosynthetic Evidencementioning

confidence: 99%

“…In cantrast considerable evidence has been obtained by tracer studies on the biosynthesis of the tricyclic diterpenoid fungal metabolite, rosenonolactone (40). This metabolite of Tricothecium roseum shows the interesting feature of a methyl group migration.…”

Section: *mentioning

confidence: 99%

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