The main factor determining the performance of a thermal storage method is the temperature stratification in the storage tank. At the ideal stratification, the energy efficiency of the storage tank is extremely high. However, when the heat pump is applied, the stratification is disrupted by heat exchange between the layers of the heat medium, and consequent convection in the tank. Therefore, this study analyzed the influence of stratification-related design factors in the water-piping facility area outside a tank heated by a heat pump. In particular, it assessed the thermal stratification and energy efficiency in the storage tank installed with a mixing valve. In the system using the mixing valve, hot water of constant temperature was supplied to the top of the storage tank, reducing the mixing effect of the hot and cold waters; consequently, the stratification index was maximized at 0.42. Comparing the times at which the temperature of the uppermost part reached 70°C in the systems with and without the mixing valve (30 and 75 min, respectively), we find that the mixing valve reduced the time of obtaining effectively hot water by approximately 60%.