Methods of synthesis of conjugated ω-amino ketones

Abstract

Simultaneous analysis of the effective moment of inertia as a function of (hw)' and of i(o) = I~pe(o) -IORB(W) indicates that the yrast negative-parity band (NPB) in 232Thexperiences an unexpected band crossing between Z x = 9 -and 13-. These spins are significantly lower than those predicted before at I= 21-25. In the NPB of 23a'238U such band crossing is not observed at these low spins.

Basicity of the polydentate captodative aminoenones. Ab initio , DFT, and FTIR study

“…Over the last few decades, enamines bearing the electron withdrawing group (EWG) at the α ‐olefinic or β ‐olefinic carbon atom have become highly attractive because of both their multifunctionality and intriguing and sometimes surprising reactivity. The first group of derivatives is termed captodative aminoalkenes ( I ) and the second, the push–pull aminoalkenes ( II ) (Chart ) . Both types of compounds are versatile building blocks in the syntheses of biologically active derivatives and natural product analogues.…”