A novel system to monitor methane fugitive emissions was developed using passive optical sensors to attend to the natural gas production and transportation industry. The system is based on optical time domain reflectometry and direct optical absorption spectroscopy. The system was tested in a gas compressor station for four months. The system was capable to measure methane concentration at two points showing its correlation with meteorological data, specially wind velocity and local temperature. Methane concentrations varied from 2.5% to 15% in the first monitored point by sensor 1, and from 5% to 30%, in the second point with sensor 2. Both sensors exhibited a moderate negative correlation with wind velocity with a mean Pearson coefficient of −0.61, despite the external cap designed to avoid the influence of wind. Sensor 2 had a modification to its external package that reduced this mean correlation coefficient to −0.30, considered to be weak to negligible. Regarding temperature, a moderate mean correlation of −0.59 was verified for sensor 1 and zero mean correlation was found for sensor 2. Based on these results the system was proven to be robust for installation in gas transportation or processing facilities.Thus, the management of atmospheric emissions and the improvement of the operational safety of gas transport infrastructures constitute an important area of research and development.Many optical fiber techniques have been reported to detect gases, including the development of micro and nano-engineered optical fibers, such as hollow-core fibers, suspended-core fibers, and tapered optical micro/nano fibers [3,4].Among the possible technologies to be employed in optical gas detection systems, the use of long period grating (LPG) coated with special material have been proposed and tested. In [5], an LPG coated with atactic polystyrene was developed and tested in a railway environment to enable the detection of liquefied petroleum gas, specifically butane gas-the main component of liquefied petroleum gas. In [6], a long-period fiber grating is proposed as a methane sensor by the deposition of high refractive index polycarbonate/cryptophane A overlay. The sensor presented a sensitivity of ∼2.5 nm.% −1 and detection limit of 0.2%. Although the measurement of gas absorption with LPG technology depends on the interaction of a specific coating, and not from the direct optical interaction itself, this technology is interesting as it enables multiplexing and the use of different coatings that could permit the detection of many substances.Other studies were carried out regarding the multiplexing capability of the gas sensor systems. In [7,8], the authors reported multiplexed multi-point gas detection where hundreds of sensors can be accessed using spatial or time division multiplexing techniques. This technique requires the use of optical delay lines and optical couplers, increasing the complexity of the optical network. One particular proposed system to monitor methane leakage with optical fiber technology is commerci...