Metallorganische chemie in fester phase: Umlagerungs-, eliminierungs-und additionsreaktionen von organometallverbindungen ohne solvens

Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species

“…An interesting case of ligand displacement, in as much as that cleavage of a dimer is occurring in the solid state, comes from the reaction shown in scheme 2 in which Werner and co-workers [ 45 ] reported that addition of CO or ethene to a chloride-bridged Rh(I) dimer resulted in the generation of monomeric species, where two dative Rh–Cl bonds had been cleaved by CO or ethene. Other examples of ligand of displacement in the solid state have been reported.…”

Recent Mechanistic and Synthetic Developments in the Chemistry of Transition‐Metal Vinylidene Complexes

“…These findings were pivotal in the development of the "oxidative-addition" pathway for the formation of metal vinylidene complexes. [25,[40][41][42][43][44][45][46] Despite the initial reports in this area being published over 25 years ago, the precise mechanism that connects the three compounds has been the subject of a considerable number of recent experimental and theoretical studies. Much of this work has been focused specifically on the conversion of the alkynyl hydride species to the corresponding vinylidene complexes.…”

Organic Solid-State Reactions with 100% Yield

“…Conversely, the corresponding h 3 -2,3,4-trans-butadienyl complexes are obtained in benzene solution at 50°C [136]. Furthermore, the quantitative rearrangement of the rhodium complex 426 to give 427 is stereoselective [137]. Further reactions of that type are reported [137].…”

“…Furthermore, the quantitative rearrangement of the rhodium complex 426 to give 427 is stereoselective [137]. Further reactions of that type are reported [137].…”