1956
DOI: 10.1007/bf00629390
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Metallkatalytische L�sung der Peptidbindung

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Cited by 16 publications
(11 citation statements)
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“…Interestingly, while 3 helped to reduce Zr IV precipitation, peptide hydrolysis by Zr IV was decreased when Tris was added [35]. This observation led us to speculate that hydrolysis of peptides by Zr IV /4,13-diaza-18-crown-6 might have a heterogeneous component similar to peptide hydrolysis by lanthanide hydroxide gels [64][65][66]80].…”
Section: Zirconium(iv)mentioning
confidence: 90%
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“…Interestingly, while 3 helped to reduce Zr IV precipitation, peptide hydrolysis by Zr IV was decreased when Tris was added [35]. This observation led us to speculate that hydrolysis of peptides by Zr IV /4,13-diaza-18-crown-6 might have a heterogeneous component similar to peptide hydrolysis by lanthanide hydroxide gels [64][65][66]80].…”
Section: Zirconium(iv)mentioning
confidence: 90%
“…Cerium(IV) is the only lanthanide with an accessible +4 oxidation state and has enhanced Lewis acid strength imparted by its high positive charge density. Thus, it is not surprising that peptide hydrolysis by Ce IV has consistently been found to be superior in comparison to other lanthanide ions (e.g., La III , Ce III , Pr III , Nd III , Sm III , Eu III , Gd III , Tb III , Dy III , Ho III , Er III , Tm III , Yb III ) [64,65,72,80]. This result can be accounted for by the exceptional ability of Ce IV to activate the peptide amide carbonyl towards nucleophilic attack.…”
Section: Hydrolysis Of Peptides and Proteins By Metal Ions And Complementioning
confidence: 94%
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