Surface-enhanced Raman spectroscopy (SERS) technology
usually uses
metallic nanoparticles to enhance Raman scattering signals, thereby
significantly adding to molecule-level recognition and detection.
However, realization of nanometer-scaled SERS imaging in liquid environments
is extremely difficult due to the requirements of both precise scanning
of single metallic nanoparticle and high enhancement field and thus
has never been achieved before. To overcome this obstacle, we demonstrate
an immersive nanometer-scaled SERS mapping technology, based on dynamic
scanning of a single metallic nanoparticle with a plasmonic-thermoelectric
nanotweezers system. The technology offers greater stability in the
plasmonic trapping of gold nanoparticles at relative low power, as
well as generating higher electric fields in the gap region. Through
its dynamics, two-dimensional nanometer-scaled SERS imaging is achieved
successfully. In regard to in liquid environments, this technology
provides a mapping method for label-free imaging of ultrathin materials,
structures, and biological samples.