Metalation of cyclopentadienyltricarbonylmanganese

Magnetic Behavior of Carboxylate and β-Diketonate Lanthanide Complexes Containing Stable Organometallic Moieties in the Core-Forming Ligand

“…The following commercial reagents and solvents were used for the syntheses: hydrated dysprosium salts Dy(NO 3 [47]. Before use in the synthesis, cymantrenecarboxylic acid was sublimed in vacuo to remove traces of Mn 2+ .…”

Novel heterometallic polymeric lanthanide acetylacetonates with bridging cymantrenecarboxylate groups – synthesis, magnetism and thermolysis

“…Cymantrenecarboxylic acid was synthesized according to a known procedure [8]. Before use in the synthesis, it was sublimed in vacuo to remove traces of Mn 2+ .…”

Supramolecular interactions in the structures of carboxylate derivatives of cymantrene and single-charged cations

“…Cymantrenecarboxylic acid HL (I) was obtained according to a known procedure [11] by reaction of cymantrenyllithium obtained from n-butyllithium and cymantrene in THF at À45°C, with solid CO 2 . The resulting lithium salt was extracted with water from the residue after evaporation of the reaction mixture; the free acid (HL) was isolated by treatment of the aqueous solution with hydrochloric acid.…”