Metal Salt and Non-Electrolyte Separation by Means of Dialysis through the Composite Membranes

Abstract

To separate salts of metals and non-electrolytes, the approach of dialysis through the composite membranes (CMs) is proposed. CM is a combination of cation and anion exchange areas. In the composite membrane, cations and anions are transferred through the respective exchange areas simultaneously without violation of macroscopic electro-neutrality. This provides a better transfer of salts than conventional ion exchange membranes (IEMs). The dialysis of the ethylene glycol aqueous salt solutions through the CMs was investigated. We have shown that the transport of salts through the composite membranes is more intensive (unlike IEM providing no transfer of salts from weakly mineralized aqueous solutions due to the Donnan exclusion) and the ethylene glycol transfer is not very significant, that is the basis of effective separation. The possibility to use of composite membranes for metal salt and other electrolyte separation is discussed.

Separation of ethylene glycol and alkali metal salts on carbon nanotubes and mosaic membranes

“…Îíè áîëåå ïðîñòû â èçãîòîâëåíèè âñëåäñòâèå îòñóòñòâèÿ òðåáîâàíèÿ ïàðàëëåëüíîñòè êàòèîíî-è àíèîíîîáìåííûõ îáëàñòåé, à èõ ñòîèìîñòü ñðàâíèìà ñî ñòîèìîñòüþ êîììåð÷åñêè äîñòóïíûõ èîíîîáìåííûõ ìåìáðàí.  ëèòåðàòóðå îòñóòñòâóþò èññëåäîâàíèÿ ïî ïåðåíîñó ÷åðåç òàêèå ÌÌ îð-ãàíè÷åñêèõ ñîåäèíåíèé è ñîëåé ìåòàëëîâ, çà èñêëþ÷åíèåì íàøåé ðàáîòû [18].…”

“… îáî-çíà÷åíèè ìîçàè÷íûõ ìåìáðàí ÀÊ-N ÷èñëî N ïîêàçûâàåò ïðîöåíòíîå ñîäåðaeàíèå àíèîíîîáìåííîé ñîñòàâëÿþùåé â èîíîîáìåííîì ìàòåðèàëå ìåìáðàíû.  ðàáîòå [18] ðàññìîòðåíû ÌÌ ñ N = 30, 45 è 80 è ïîêàçàíî, ÷òî íàèáîëåå ýôôåêòèâíûé ïåðåíîñ ñîëè íàáëþäàåòñÿ ïðè äèàëèçå ÷åðåç ÀÊ-45. Åñëè êàòèîíîîáìåííàÿ ÷àñòü ìåìáðàíû ÀÊ íàõîäèòñÿ â Na-ôîðìå, à àíèîíîîáìåííàÿ ÷àñòü -â Cl-ôîðìå, òî ãîâîðÿò, ÷òî ìåìáðàíà íàõîäèòñÿ â NaCl-ôîðìå.…”