Metal−Peptide Frameworks (MPFs):  “Bioinspired” Metal Organic Frameworks

Mantion, Alexandre; Massüger, Lars; Rabu, Pierre; Palivan, Cornelia G.; McCusker, Lynne B.; Taubert, Andreas

doi:10.1021/ja0762588

Cited by 169 publications

(116 citation statements)

References 62 publications

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“…In 2008, Taubert and Mantion et al reported the fi rst example of metal peptide frameworks (MPFs) 28, also termed "bioinspired" analogues to the wellknown MOFs, assembled from an oligovaline peptide Z-(LVal) 2 -L-Glu(OH)-OH through metal-oxygen and metal-nitrogen bonding and various types of hydrogen bonding along with π … π stacking ( Figure 12 ). [ 80 ] The structure of MPF 28 can be described in terms of two 2D substructures interconnected via hydrogen bonding, i.e. the fi rst is a double layer of copper ions in the ab plane that are diagonally displaced with respect to one another, and the second double layer in the ab plane is that of the peptide with its long molecule axis oriented roughly along [001].…”

Section: Reviewmentioning

confidence: 99%

Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

2010

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Owing to the potential applications in technological areas such as gas storage, catalysis, separation, sensing and nonlinear optics, tremendous efforts have been devoted to the development of porous metal-organic frameworks (MOFs) over the past ten years. Homochiral porous MOFs are particularly attractive candidates as heterogeneous asymmetric catalysts and enantioselective adsorbents and separators for production of optically active organic compounds due to the lack of homochiral inorganic porous materials such as zeolites. In this review, we summarize the recent research progress in homochiral MOF materials, including their synthetic strategy, distinctive structural features and latest advances in asymmetric heterogeneous catalysis and enantioselective separation.

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Section: Reviewmentioning

confidence: 99%

Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

2010

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“…For example, it should be possible to adsorb targeted molecules if specific interactions sites are suitably located on regular micropores. [40] With this principle, MOFs with pores containing fullerenes, [41] peptides [42] or specific chirality [43,44] have been reported and studied. Although a range of functional MOFs have been produced through ligand design, it is also noteworthy that many functional groups cannot survive the severe MOF formation conditions (e.g., pH, temperature) and impede the formation of the reticular frameworks.…”

Section: Metal-organic Framework (Mofs)mentioning

confidence: 99%

Metal‐Containing Polymers: Building Blocks for Functional (Nano)Materials

Wang¹,

McHale²

2010

Macromol. Rapid Commun.

113

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The incorporation of metallic units into polymer chains has emerged as a promising route towards functional metal-containing (nano)materials. The resulting polymers possess rich functions derived from their metallic elements, such as redox, optical, catalytic and magnetic properties. In addition, the directional and dynamic nature of metal coordination interactions provides further variables for the exploration of novel materials with designed nanostructures. These types of polymers can be synthesized through direct metal-ligand coordination or chain polymerization of metal containing monomers. Depending on the polymerization techniques and starting components, the resulting polymers, akin to their organic counterparts, can be produced in the form of insoluble networks, processible chain structures, gels or colloids. Research into this rising multidisciplinary subject has benefited from recent progress in several related areas such as supramolecular chemistry, colloidal chemistry etc., with the combination of the relative merits of each ensuring further developments in each individual discipline. For example, as a result of studies into organometallic block copolymers self-assembly behavior, living supramolecular polymerization has been unprecedentedly realized for the architectural design of micelles (see image on the right). Nevertheless, the field is still in a developmental stage and offers ample opportunities for fundamental research, as well as material exploration. In this Feature Article, we intend to overview the field with a brief survey of recent literature.

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“…Selected IR data (KBr disc, cm −1 ): 3287,3063,2976,2867,2560,1713,1643,1536,1434,1408,1340,1325,1295,1269,1243,1072,1026,1002,919,895,819,738,673,644. (2). The same procedure was followed for the preparation of all compounds, so only the synthesis of 2 is described in detail.…”

Section: Synthetic Partmentioning

confidence: 99%

“…2 In addition, coordination polymers based on amino acid backbones have gained widespread interest due to their intriguing properties such as asymmetric catalysis, chiral sorption, etc.…”

Section: Introductionmentioning

confidence: 99%

Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions

Dokorou¹,

Milios²,

Tsipis³

et al. 2012

Dalton Trans.

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(2012) Pseudopeptidic ligands: exploring the selfassembly of isopthaloylbisglycine (H2IBG) and divalent metal ions. Dalton Transactions, 41. pp. 12501-12513. ISSN 1477-9226 This version is available from Sussex Research Online: http://sro.sussex.ac.uk/46681/ This document is made available in accordance with publisher policies and may differ from the published version or from the version of record. If you wish to cite this item you are advised to consult the publisher's version. Please see the URL above for details on accessing the published version. Copyright and reuse:Sussex Research Online is a digital repository of the research output of the University.Copyright and all moral rights to the version of the paper presented here belong to the individual author(s) and/or other copyright owners. To the extent reasonable and practicable, the material made available in SRO has been checked for eligibility before being made available.Copies of full text items generally can be reproduced, displayed or performed and given to third parties in any format or medium for personal research or study, educational, or not-for-profit purposes without prior permission or charge, provided that the authors, title and full bibliographic details are credited, a hyperlink and/or URL is given for the original metadata page and the content is not changed in any way. We present a systematic study of the complexation of the new pseudopeptidic ligand isophthaloylbisglycine (H 2 IBG) with divalent metal ions of varying ionic radius. This work represents the initial employment of H 2 IBG in the coordination chemistry of alkaline earth, 3d transition, Zn(II) and Cd(II) metal elements. Infrared, NMR, thermal, magnetic, adsorption and theoretical studies of these compounds are also discussed. Dalton Transactions

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Metal−Peptide Frameworks (MPFs): “Bioinspired” Metal Organic Frameworks

Cited by 169 publications

References 62 publications

Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

Metal‐Containing Polymers: Building Blocks for Functional (Nano)Materials

Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions

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