Metal–Organic Gels

Zhang, Jianyong; Hu, Ya; Li, Yongguang

doi:10.1007/978-981-10-6881-2_3

Cited by 4 publications

(2 citation statements)

References 131 publications

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“…[1,18a,21] The sol state is a colloidal network of discrete crystalline nanoparticles, which are stabilized by weak noncovalent interactions throughout the liquid phase to maintain a stable colloidal state. [22] D. De. Vos et al [17c] prepared UiO-66 sol, which showed high viscoelasticity.…”

Section: Synthesis Strategy and Mechanismmentioning

confidence: 99%

Direct Synthesis of Metal–Organic Framework Sols: Advances and Perspectives

Xie,

Yuan,

2023

Chemistry An Asian Journal

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The intrinsic lack of processability in the conventional nano/microcrystalline powder form of metal‐organic frameworks (MOFs) greatly limits their application in various fields. Synthesis of MOFs with certain flowability make them promising for multitudinous applications. The direct synthesis strategy represents one of the simplest and efficient method for synthesizing solution processable MOF sols/suspensions, compared with other approaches, for instance, the post‐synthesis surface modification, the direct dispersion of MOFs in hindered ionic liquids, as well as the calcination method toward a few MOFs with melting behavior. This article reviews the recent direct synthesis strategies of solution processable MOF sols and their typical applications in different fields. The direct synthesis strategies of MOF sols can be classified into two categories: particle size reduction strategy, and selective coordination strategy. The synthesis mechanism of different strategies and the factors affecting the formation of sols are summarized. The application of solution processable MOF sols in different fields are introduced, showing great application potentials. Furthermore, the challenges faced by the direct synthesis of MOF sols and the main methods to deal with the challenges are emphasized, and the future development trend is prospected.

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Section: Synthesis Strategy and Mechanismmentioning

confidence: 99%

Direct Synthesis of Metal–Organic Framework Sols: Advances and Perspectives

Xie,

Yuan,

2023

Chemistry An Asian Journal

View full text Add to dashboard Cite

show abstract

“…[27][28][29][30] Self-assembly of low molecular weight gelators (LMWGs) has led to a sweet of so materials in the area of drug delivery systems, tissue engineering scaffolds, cosmetics, indicators, and sensors. [31][32][33][34] To bring out the potency of these so materials in denitive manners for specic applications, tuning of multiple non-covalent interactions such as hydrogen bonding, p-p stacking, electrostatic effects, and van der Waals forces, can be helpful. [35][36][37][38][39] In recent years metallogels have drawn attention, due to their broad range of applications.…”

Section: Introductionmentioning

confidence: 99%