Metal-organic frameworks based membrane as a permselective separator for lithium-sulfur batteries

Suriyakumar, Shruti; Kanagaraj, M.; Kathiresan, Murugavel; Angulakshmi, N.; Thomas, Sabu; Stephan, A. Manuel

doi:10.1016/j.electacta.2018.01.155

Cited by 80 publications

(45 citation statements)

References 28 publications

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“…1 shows the structure of TP-POP prepared from the nucleophilic substitution reaction of cyanuric chloride with 1,4-phenylenediamine in the presence of a base. The as prepared POP sample was then characterized by 1 H, 13 C and 15 N NMR, and the obtained results are in accordance with earlier reports and are given as ESI † (Fig. S1a-c).…”

Section: Synthesis Of Triazine-phenylenediamine-porous Organic Polymesupporting

confidence: 88%

“…Multifunctional membrane separators with permselectivity or localizing abilities placed between the cathode and the anode play a crucial role not only in preventing electrical short circuit and transportation of the ions between the cathode and the anode, but also in suppressing the migration of polysulfides, increasing the reactivation of some species that contain dead sulfur, and preventing the formation of dendrites on the lithium anode surface. [12][13][14] The use of several membrane designs based on various functional groups with negative surface charge as polysulfide blocking layers in Li-S batteries has been examined, amongst which Nafion, 15 graphene oxide, 16 and MOFs 17 have received the most attention.…”

Section: Introductionmentioning

confidence: 99%

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A porous organic polymer-coated permselective separator mitigating self-discharge of lithium–sulfur batteries

et al. 2020

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Section: Synthesis Of Triazine-phenylenediamine-porous Organic Polymesupporting

confidence: 88%

Section: Introductionmentioning

confidence: 99%

A porous organic polymer-coated permselective separator mitigating self-discharge of lithium–sulfur batteries

et al. 2020

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“…After Bai et al.’s work above, the research and development of MOF‐based separators have blossomed. For example, Zn(II)‐MOF‐based, Mn‐BTC‐coated, NH 2 ‐MIL‐125(Ti)‐coated, UiO‐66‐NH 2 @SiO 2 ‐coated, electrically conductive Ni 3 (HITP) 2 ‐modified, Ni‐MOF/MWCNT‐coated, and CNT@ZIF‐functionalized separators have been reported to mitigate the shuttle effect by either physical blocking or Lewis acid‐base interactions. However, it is still possible for polysulfides to diffuse through the grain boundaries or voids of the MOF coatings during long‐term cycling, similar to what happens with MOF‐based mixed‐matrix membranes for gas separations.…”

Section: Mofs For Lithium‐sulfur Batteriesmentioning

confidence: 99%

Metal−Organic Frameworks for High‐Energy Lithium Batteries with Enhanced Safety: Recent Progress and Future Perspectives

Zhang

Dong

Song

2019

Batteries & Supercaps

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frameworks (MOFs) are a relatively new class of crystalline, highly-porous organic-inorganic hybrid materials that have been attracting increasing attention in the field of high-energy lithium batteries. In this review, recent achievements are detailed regarding the innovative design and processing of pristine MOFs and their nanocomposites for lithiumÀsulfur and lithiumÀoxygen batteries with high specific energy. Furthermore, the benefits and challenges associated with the applications of MOF-based materials in solid-state lithium-metal batteries are discussed. Lastly, future prospects for the rational design and manufacturing of MOF-based materials are provided.can also be used as Li-ion conductors for all-solid-state electrolytes, wherein Li + ions can be fast mobilized along open metal sites. [12d,16] There are several good review articles addressing MOFderived materials (e. g., porous carbon or metal oxides) for energy storage applications, [10,17] which are not covered in detail in this review. Here, a comprehensive overview is provided that focuses on recent advancement in pristine MOFs and their nanocomposites for emerging high-energy Li batteries (LiÀS, LiÀO 2 , and solid-state Li-metal batteries). Furthermore, the advantages and challenges associated with the development of MOF-based materials are discussed. Lastly, the future prospects for the rational design and manufacturing of MOF-based materials are outlined. 2 3 4 5 6 7 8

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“…117 From a different point of view, the insulating nature of many MOFs in turn can be an advantage when MOFs are employed as separators in LSBs. 71,118,119 Moreover, the highly ordered and tunable pore structures of MOFs as separators are beneficial for suppressing the shuttling of soluble lithium polysulfides.…”

Section: Lithium-sulfur Batteriesmentioning

confidence: 99%

Metal-Organic Frameworks for Batteries

Zhao

Liang

Zou

et al. 2018

Joule

514

294

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Metal-organic frameworks (MOFs) and their derivatives are two developing families of functional materials for energy storage and conversion. Their high porosity, versatile functionalities, diverse structures, and controllable chemical compositions offer immense possibilities in the search for adequate electrode materials for rechargeable batteries. Despite these advantageous features, MOFs and their derivatives as electrode materials face various challenging issues, which impede their practical applications. From this perspective, we present both the opportunities and challenges that MOFs/MOF composites and MOF-derived materials bring to rechargeable batteries, including lithium-ion batteries, lithium-sulfur batteries, lithium-oxygen batteries, and sodium-ion batteries. By discussing the development of MOFs/MOF composites and MOF-derived materials in each battery system, some design principles that dominate the specific electrochemical behaviors are outlined, with the key requirements that a practical electrode should fulfill. At the end, a basic guidance and future directions for further development are provided.

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Metal-organic frameworks based membrane as a permselective separator for lithium-sulfur batteries

Cited by 80 publications

References 28 publications

A porous organic polymer-coated permselective separator mitigating self-discharge of lithium–sulfur batteries

A porous organic polymer-coated permselective separator mitigating self-discharge of lithium–sulfur batteries

Metal−Organic Frameworks for High‐Energy Lithium Batteries with Enhanced Safety: Recent Progress and Future Perspectives

Metal-Organic Frameworks for Batteries

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