Metal–Organic Frameworks‐Based Cathode Materials for Energy Storage Applications: A Review

Abstract

Metal-organic framework (MOF) are a kind of highly organized porous crystalline material that has attracted significant interest in several applications, including chemical sensors, organic-, photo-, and electrocatalysis, and energy and environmental applications. [1][2][3][4][5][6] Yaghi et al. are pioneers in the development of MOF-based porous materials using organic linkers and metal-oxide clusters as anchors to create open frameworks. [7] MOFs are readily manufactured by reacting metal ions or clusters with organic linkers in the presence of aqueous or organic solvents at certain temperatures, resulting in crystalline powders or granules. [8] The use of solvent is also playing an effective role in the synthesis of uniform MOFs in addition to other parameters. The solvent used in synthesis remains inside the pores of the collected crystalline framework. These holes may be cleaned out using a more volatile solvent and vacuum-aided desorption, leaving behind an enormous void pore volume. [8] These activated MOFs are calcined further to operate for target-specific analyte adsorption and applications. By varying the chemical compositions of metal and organic linkers, a highly adaptable and adjustable porous architecture may be readily created. [9] MOFs may also provide different internal surfaces with distinct accessible metal sites, various structural topologies, and chemical variety, such as the usage of

Recent advances in two-dimensional MXenes for zinc-ion batteries

“…At present, materials with more research on the cathode of ZIBs mainly include manganese-based, vanadium-based, Prussian blue, and some conductive organic materials. [73][74][75][76] Among them, manganese-based and vanadium-based oxides are the most widely studied cathode materials. Manganese-based oxides have high working voltage and high theoretical capacity for zinc storage.…”

Advances and Applications of Metal‐Organic Frameworks (MOFs) in Emerging Technologies: A Comprehensive Review

“…[50,52,54,190] Furthermore, MOF materials possess characteristics such as large surface area, tunable porosity, flexible topology, flexible dimension, and chemical functionality, making them of wide interest in the field of energy harvesting and storage. [2,[191][192][193][194] Multiple works have reported the application of MOF in highperformance TENG. [53,56,[195][196][197][198] For instance, Khandelwal et al first reported the use of zeolitic imidazole framework (ZIF) MOF-based TENG for self-powering systems and sensor applications (Figure 8a).…”

Life Cycle Assessment of Energy Storage Technologies for New Power Systems under Dual‐Carbon Target: A Review

“…In the past few decades, several studies have extensively investigated the application of ESTs in renewable energy grid connection, [9][10][11] distributed generation and microgrid, [12][13][14] electric vehicle energy storage applications, [15][16][17] and power transmission. [18][19][20] The article in ref.…”